2012 Fiscal Year Final Research Report
Synthesis of amphiphilic liquid crystalline multiblock copolymer films and evaluation of their microphase separation structure
| Project/Area Number |
23750252
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Kochi University (2012)
Tokyo Institute of Technology (2011) |
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Principal Investigator |
HADANO Shingo 高知大学, 教育研究部総合科学系, 助教 (70397157)
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| Project Period (FY) |
2011 – 2012
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| Keywords | 両親媒性ブロックコポリマー / ミクロ相分離構造 / 熱物性 / テンプレート / 液晶 |
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| Research Abstract |
ABA-, A2B-, and A2BA2 type “multi”block copolymers consisting of hydrophobic and liquid crystalline polymethacrylate as A-block and hydrophilic poly(ethylene oxide) as B-block were synthesized to make smaller microphase separation structure with keeping film forming ability of the resulting multiblock copolymers. As a result, ABA triblock copolymers exhibited a half-sized microphase separation structure when the total molecular weight and the molecular weight of B-block in ABA triblock copolymers were same to those in AB diblock copolymers.
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