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2013 Fiscal Year Final Research Report

In-situ and atomic-scale observation of nano-scale ferroelectric domain structure

Research Project

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Project/Area Number 23760632
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionThe University of Tokyo

Principal Investigator

SATO Yukio  東京大学, 工学(系)研究科(研究院), 助教 (80581991)

Project Period (FY) 2011 – 2013
Keywords強誘電体 / ドメイン / 圧電体 / 透過型電子顕微鏡法 / その場観察 / 結晶構造 / 電子回折 / 原子配列
Research Abstract

Piezoelectric material, which deforms largely when electrical voltage is applied, is widely used in a variety of practical applications. Particularly, PMN-PT, a representative piezoelectric material, exhibits very high piezoelectricity. However, mechanism of the high piezoelectricity has not yet been clarified.
In the present study, in order to understand the origin of high piezoelectricity, in-situ transmission electron microscopy (TEM) and atomic resolution scanning TEM observations were carried out.
We have for the first time visualized the response of ferroelectric nanodomains to the applied electrical voltage, where the ferroelectric nanodomains are characteristic structure in PMN-PT. On the basis of results obtained in this research project, we have proposed that response of ferroelectric nanodomains plays very important role in the generation of very high piezoelectricity of this material.

  • Research Products

    (15 results)

All 2014 2013 2012 2011 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (8 results) (of which Invited: 8 results) Remarks (3 results)

  • [Journal Article] Monoclinic nanodomains in morphotropic phase boundary Pb(Mg_1/3Nb_2/3)O_3-PbTiO_32014

    • Author(s)
      Y. Sato, T. Hirayama, and Y. Ikuhara
    • Journal Title

      Applied Physics Letters

      Volume: 104巻 Pages: 082905-1-3

    • DOI

      10.1063/1.4866791

    • Peer Reviewed
  • [Journal Article] Real-Space Distribution of Local WO_4 Ordering in Negative Thermal Expansive ZrW_2O_82012

    • Author(s)
      Y. Sato, Y. Yamamura, K. Saito, and Y. Ikuhara
    • Journal Title

      Journal of the American Chemical Society

      Volume: 134巻 Pages: 13942-13945

    • DOI

      10.1021/ja305456j

    • Peer Reviewed
  • [Journal Article] Evolution of nanodomains under DC electrical bias in Pb(Mg_1/3Nb_2/3)O_3-PbTiO_3 : An In-situ transmission electron microscopy study2012

    • Author(s)
      Y. Sato, T. Hirayama, and Y. Ikuhara
    • Journal Title

      Applied Physics Letters

      Volume: 100巻 Pages: 172902-1-3

    • DOI

      10.1063/1.4705418

    • Peer Reviewed
  • [Journal Article] Real-Time Direct Observations of Polarization Reversal in a Piezoelectric Crystal : Pb(Mg_1/3Nb_2/3)O_3-PbTiO_3 Studied via In Situ Electrical Biasing Transmission Electron Microscopy2011

    • Author(s)
      Y. Sato, T. Hirayama, and Y. Ikuhara
    • Journal Title

      Physical Review Letters

      Volume: 107巻 Pages: 87601-1-5

    • DOI

      10.1103/PhysRevLett.107.187601

    • Peer Reviewed
  • [Presentation] Role of Grain Boundaries in ZnO2014

    • Author(s)
      Y. Sato and Y. Ikuhara
    • Organizer
      SPIE Photonics West 2014
    • Place of Presentation
      The Moscone Center, San Fransisco, USA
    • Year and Date
      2014-02-03
    • Invited
  • [Presentation] 電子セラミックスにおける微視的な構造および物性への影響2013

    • Author(s)
      佐藤幸生
    • Organizer
      日本顕微鏡学会第57回シンポジウム
    • Place of Presentation
      ウインク愛知,愛知
    • Year and Date
      2013-11-16
    • Invited
  • [Presentation] 電子セラミックスにおける微視的な構造および物性への影響2013

    • Author(s)
      佐藤幸生
    • Organizer
      日本金属学会・鉄鋼協会九州支部・平成25年度材料プロセス談話会特別講演会
    • Place of Presentation
      九州大学,福岡
    • Year and Date
      2013-06-21
    • Invited
  • [Presentation] 電子セラミックスにおける微細構造と物性の相関に関する研究2013

    • Author(s)
      佐藤幸生
    • Organizer
      2013年日本セラミックス協会年会
    • Place of Presentation
      東京工業大学,東京
    • Year and Date
      2013-03-18
    • Invited
  • [Presentation] Domain response by electric fields in PMN-PT : An in-situ transmission electron microscopy study2012

    • Author(s)
      Y. Sato, T. Hirayama, and Y. Ikuhara
    • Organizer
      The 9th Korea-Japan Conference on Ferroelectrics (KJC-FE09)
    • Place of Presentation
      University of Ulsan, Ulsan, Korea
    • Year and Date
      2012-08-10
    • Invited
  • [Presentation] 透過型電子顕微鏡法を用いたセラミック材料の解析2011

    • Author(s)
      佐藤幸生
    • Organizer
      第120回強誘電体研究会
    • Place of Presentation
      東京理科大学,東京
    • Year and Date
      2011-12-16
    • Invited
  • [Presentation] 若手研究者の皆様へ~これまでの体験談から~2011

    • Author(s)
      佐藤幸生
    • Organizer
      特定領域研究「ナノ機能元素の材料科学」第4回若手の会
    • Place of Presentation
      東京理科大学,師崎荘,愛知
    • Year and Date
      2011-09-28
    • Invited
  • [Presentation] Atomic-scale investigations of nano-scale regions in electroceramics through scanning transmission electron microscopy2011

    • Author(s)
      Y. Sato, T. Mizoguchi, N. Shibata, T. Yamamoto, T. Hirayama, and Y. Ikuhara
    • Organizer
      5th Meeting of the International Union of Microbeam Analysis Societies (IUMAS-V)
    • Place of Presentation
      Seoul Olympic parktel, Seoul, Korea
    • Year and Date
      2011-05-23
    • Invited
  • [Remarks]

    • URL

      http://zaiko13.zaiko.kyushu-u.ac.jp/sato.html

  • [Remarks] 日経産業新聞 「圧電材料の分子観察」,平成23年11月9日 新聞発表

  • [Remarks] 日刊工業新聞 「圧電セラのナノ領域応答,即時直接観察に成功」,平成23年10月31日 新聞発表

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Published: 2015-06-25  

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