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2012 Fiscal Year Final Research Report

Development of hydrodeoxygenation catalysts for conversion of biomass lignin

Research Project

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Project/Area Number 23760737
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionTohoku University

Principal Investigator

NAKAGAWA Yoshinao  東北大学, 工学研究科, 助教 (10436545)

Project Period (FY) 2011 – 2012
Keywords資源 / エネルギー利用技術
Research Abstract

Hydrodeoxygenation of biomass-lignin-derived compounds has been investigated using guaiacol as a model substrate. Both multi-step process and single-step process were developed. The multi-step process involves steps using Rh catalyst, Ru catalyst, and Ir-ReOx catalyst. Cyclohexanol was obtained in good yield. The single-step process uses Ru catalyst and base co-catalyst, giving high yield of cyclohexanol.

  • Research Products

    (13 results)

All 2013 2012

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (6 results)

  • [Journal Article] One-Pot Conversion of Sugar and Sugar Polyols to n-Alkanes without C-C Dissociation over the Ir-ReO_x/SiO_2 Catalyst Combined with H-ZSM-52013

    • Author(s)
      Kaiyou Chen, Masazumi Tamura, Zhenle Yuan, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      ChemCatChem

      Volume: 6巻 Pages: 613-621

    • DOI

      DOI:10.1002/cssc.201200940

    • Peer Reviewed
  • [Journal Article] Performance, structureand mechanism of Pd-Ag alloy catalyst for selective oxidation of glycerol to dihydroxyacetone2013

    • Author(s)
      Shota Hirasawa, Hideo Watanabe, Tokushi Kizuka, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      Journal of Catalysis

      Volume: 300巻 Pages: 205-216

    • DOI

      DOI:10.1016/j.jcat.2013.01.014

    • Peer Reviewed
  • [Journal Article] Production of Biobutanediols by the Hydrogenolysis of Erythritol2012

    • Author(s)
      Yasushi Amada, Hideo Watanabe, Yuichirou Hirai, Yasuteru Kajikawa, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      ChemSusChem

      Volume: 5巻 Pages: 1991-1999

    • DOI

      DOI:10.1002/cssc.201200121

    • Peer Reviewed
  • [Journal Article] Total Hydrogenation of Furfural over aSilica-Supported Nickel Catalyst Prepared by the Reduction of a Nickel Nitrate Precursor2012

    • Author(s)
      Yoshinao Nakagawa, Hiroya Nakazawa, Hideo Watanabe, and Keiichi Tomishige
    • Journal Title

      ChemCatChem

      Volume: 4巻 Pages: 1791-1797

    • DOI

      DOI:10.1002/cctc.201200218

    • Peer Reviewed
  • [Journal Article] C-O bond hydrogenolysis ofcyclic ethers with OH groups over rhenium-modified supported iridium catalysts2012

    • Author(s)
      Kaiyou Chen, Kazuma Mori, Hideo Watanabe, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      Journal of Catalysis

      Volume: 294巻 Pages: 171-183

    • DOI

      DOI:10.1016/j.jcat.2012.07.015

    • Peer Reviewed
  • [Journal Article] Solid acid co-catalyst for the hydrogenolysis of glycerol to 1,3-propanediol over Ir-ReO_x/SiO_22012

    • Author(s)
      Yoshinao Nakagawa, Xuanhe Ning, Yasushi Amada, Keiichi Tomishige
    • Journal Title

      Applied Catalysis A: General

      Volume: 433-434巻 Pages: 128-134

    • DOI

      DOI:10.1016/j.apcata.2012.05.009

    • Peer Reviewed
  • [Journal Article] Selective oxidation of glycerol to dihydroxyacetone over Pd-Ag catalyst2012

    • Author(s)
      Shota Hirasawa, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      Catalysis Science and Technology

      Volume: 2巻 Pages: 1150-1152

    • DOI

      DOI:10.1039/c2cy20062g.

    • Peer Reviewed
  • [Presentation] 担持Ru触媒を用いたグアイコールの水素化分解によるシクロヘキサノール選択的合成2013

    • Author(s)
      石川桃子・田村正純・中川善直・冨重圭一
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      大阪
    • Year and Date
      2013-02-25
  • [Presentation] ReOx修飾Ir触媒を用いた環状エーテル類の水素化分解反応2012

    • Author(s)
      田村正純・陳凱幼・中川善直・冨重圭一
    • Organizer
      第42回石油・石油化学討論会
    • Place of Presentation
      秋田
    • Year and Date
      2012-10-11
  • [Presentation] Pd-Ag/Cを用いたグリセリンの酸化反応によるジヒドロキシアセトンの生成2012

    • Author(s)
      平澤祥太・中川善直・冨重圭一
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-29
  • [Presentation] ReOx修飾Ir触媒を用いたテトラヒドロフルフリルアルコールの水素化分解反応による1,5-ペンタンジオールの合成2012

    • Author(s)
      陳凱幼・中川善直・冨重圭一
    • Organizer
      第109回触媒討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-29
  • [Presentation] テトラヒドロフルフリルアルコールの水素化分解による1,5-ペンタンジオールの合成におけるレニウム修飾イリジウム触媒の反応特性2012

    • Author(s)
      森一真・陳凱幼・中川善直・冨重圭一
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27
  • [Presentation] Ir-ReO_x/SiO_2触媒のグリセリン水素化分解反応機構とエリスリトールへの応用2012

    • Author(s)
      天田靖史・寧玄鶴・梶川泰照・中川善直・冨重圭一
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27

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Published: 2014-09-25  

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