Study on Design of Multi-functionalized Heterogeneous Catalysts by Use of Layered Hydroxy Double Salt

2012 Fiscal Year Final Research Report

• Project/Area Number: 23760738
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Catalyst/Resource chemical process
• Research Institution: Chiba University
• Principal Investigator: HARA Takayoshi 千葉大学, 大学院・工学研究科, 助教 (60437358)
• Project Period (FY): 2011 – 2012
• Keywords: 触媒調製化学 / グリーンケミストリー

Research Abstract

We have developed the multi-functionalized Ni-Zn hydroxyl double salt as a heterogeneous catalystfor CO_2 fixation reaction into epoxides. The isolated Zn^<2+> cation located on Ni(OH)_2 brucite sheet canact as a Lewis acid site to activate epoxide molecule. Intercalation of ethoxide anion as a Lewis baseinto NiZn interlayer was also carried out. The obtained EtO^-/NiZn can promote the above reactioneffectively under 1 atm of CO_2. It can be said that the EtO^-/NiZn has two functions such as Lewis acidityand Lewis basicity on its matrix.

Research Products

• [Journal Article] (2013)
  • Author(s): I. B. Adilina, T. Hara, N. Ichikuni, N. Kumada,S. Shimazu
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 86 Pages: 146-152
• [Journal Article] (2012)
  • Author(s): Rodiansono, S. Khairi, T. Hara, N. Ichikuni, S.Shimazu
  • Journal Title: Catal. Sci. Technol. Volume: 2 Pages: 2139-2145
• [Journal Article] (2012)
  • Author(s): Rodiansono, T. Hara, N. Ichikuni, S. Shimazu
  • Journal Title: Chem. Lett. Volume: 41 Pages: 769-771
• [Journal Article] (2012)
  • Author(s): I. B. Adilina, T. Hara, N. Ichikuni, S. Shimazu
  • Journal Title: J.Mol. Catal. A: Chem. Pages: 361-362,72-79
• [Journal Article] (2012)
  • Author(s): T. Hara, Y. Takami, N. Ichikuni, S. Shimazu
  • Journal Title: Chem. Lett. Volume: 41 Pages: 488-490
• [Journal Article] (2012)
  • Author(s): Hara, M. Hatakeyama, A. Kim, N. Ichikuni, S.Shimazu
  • Journal Title: Green Chem. Volume: 13 Pages: 771-777
• [Journal Article] (2011)
  • Author(s): T. Hara, J. Sawada, Y. Nakamura, N. Ichikuni, S.Shimazu
  • Journal Title: Catal. Sci. Technol. Volume: 1 Pages: 1376-1382
• [Journal Article] (2011)
  • Author(s): K. Motokura, N. Hashimoto, T. Hara, T.Mitsudome, T. Mizugaki, K. Jitsukawa, K. Kaneda
  • Journal Title: Green Chem. Volume: 13 Pages: 2416-2422
• [Journal Article] (2011)
  • Author(s): D. Tsukamoto, M. Ikeda, Y. Shiraishi, T. Hara, 77N. Ichikuni, S. Tanaka, T. Hirai
  • Journal Title: Chem. Eur. J. Volume: 17 Pages: 9816-9824
• [Journal Article] (2011)
  • Author(s): Y. Takahashi, N. Hashimoto, T. Hara, S.Shimazu, T. Mitsudome, T. Mizugaki, K. Jitsukawa,K. Kaneda
  • Journal Title: Chem. Lett. Volume: 40 Pages: 405-407
• [Journal Article] (2011)
  • Author(s): Y. Ogaki, Y. Shinozuka, T. Hara, N. Ichikuni, S.Shimazu
  • Journal Title: Catal. Today Volume: 164 Pages: 415-418
• [Presentation] Rh水酸化物アニオン導入型層状Ni-Zn複塩基性塩触媒による炭素-炭素結合形成反応 (2013)
  • Author(s): 原孝佳・藤田希未・一國伸之・島津省吾
  • Organizer: 日本化学会第93春季年会
  • Place of Presentation: 草津
  • Year and Date: 20130300
• [Presentation] アニオン交換型Ni-Zn複塩基性塩触媒を用いたCO_2とエポキシドからの環状カーボネート合成 (2011)
  • Author(s): 原孝佳・中村宜央・一國伸之・島津省吾
  • Organizer: 第27回日本イオン交換研究発表会・第30回溶媒抽出討論会連合年会
  • Place of Presentation: 宮崎
  • Year and Date: 20111100
• [Presentation] 反応空間を制御した層状Ni-Zn複塩基性塩触媒による1,3-ジニトロ化合物のワンポット合成 (2011)
  • Author(s): 木澤大二郎・原孝佳・一國伸之・島津省吾
  • Organizer: 第27回日本イオン交換研究発表会・第30回溶媒抽出討論会連合年会
  • Place of Presentation: 宮崎
  • Year and Date: 20111100
• [Presentation] アニオン交換型Ni-Zn複塩基性塩触媒によるCO_2のエポキシドへの環化付加反応 (2011)
  • Author(s): 原孝佳・中村宜央・一國伸之・島津省吾
  • Organizer: 第108回触媒討論会
  • Place of Presentation: 北見
  • Year and Date: 20110900