2012 Fiscal Year Final Research Report
Development of new reactions using iron phthalocyanineand molecularoxygen
| Project/Area Number |
23790008
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2012
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| Keywords | 鉄触媒 / ラジカル反応 / 分子状酸素 / C-H 酸化 / 縮合反応 / 触媒反応 |
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| Research Abstract |
Three novel reactions using iron phthalocyanine and molecular oxygen have been developed:
(1) a new method for generation of radicals from hydrazine compounds and addition reactions of resultant radicals to alkenes
(2) synthesis of 1,4-diols from simple alkenes by redox hydration using sodium borohydride
(3) oxidation-reduction esterification using oxygen as an oxidant. In addition, mild oxynitration reactions of alkenes have been found in the courseof these studies.
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