2013 Fiscal Year Final Research Report
Synthesis of electron withdrawing cyclopentadienides as new Lewis acid catalysts
| Project/Area Number |
23790027
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Chemical pharmacy
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| Research Institution | Meijo University |
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Principal Investigator |
TAKEO Sakai 名城大学, 薬学部, 助教 (90583873)
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| Project Period (FY) |
2011 – 2013
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| Keywords | テトラシアノシクロペンタジエニド / 酸 / 触媒 / スルホン / 有機化学 |
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| Research Abstract |
Superacid conjugate bases are widely used in reagents and catalysts. We established a general synthetic method for tetracyanocyclopentadienides, one of superacid conjugate bases, from sulfones and tetracyanothiophene. Various functionalization reactions on a cyclopentadienide ring were performed to give more substituent diversity.
The hydrolysis of O-TBS-menthol was accelerated by the addition of synthesized tetracyanocyclopentadienides in dichloromethane-1 M hydrochloric acid biphase system, in which the TBS group was usually rigid.
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Research Products
(43 results)
