2012 Fiscal Year Final Research Report
Electrophilic Fluorination Using Organodication Species
| Project/Area Number |
23850005
|
|---|
| Research Category |
Grant-in-Aid for Research Activity Start-up
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | University of Tsukuba |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Keywords | 有機合成化学 |
|---|
| Research Abstract |
Treatment of the organo-dication species with a naphthalene framework with cesium fluoride afforded a fluorine-bridged cation in good yield. This protocol improved previous methodologies for preparation of similar fluorine cation species. For the future, I would like to try fluorination of organic compounds utilizing the fluorine cation thus formed, for example, via single electron transfer reactions. On the other hand, I succeeded in the preparation of another type of organo-dication species with a dihydroanthracene framework. This dication was found to serve as a strong oxidant, and effectively promoted the oxidative self-coupling of naphthols.
|
