2017 Fiscal Year Final Research Report
Exploration of Efficient Carbon Dioxide Fixations
| Project/Area Number |
24245019
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2017-03-31
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| Keywords | 二酸化炭素固定化 |
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| Outline of Final Research Achievements |
In this study, development of carbon dioxide fixation reactions with carbon-carbon bond formation was extensively studied based on the results obtained in our laboratory. Development of hydrocarboxylation reactions of styrene and electron deficient alkenes, direct C-H bond carboxylation of simple arenes, use of formate salt as a reductant in the hydrocarboxylation reaction, utilization of visible light for the reduction of carboxylate salt to metal hydride or low valent metal for catalytic hydrocarboxylation reaction and caboxylation of aryl halides were achieved by this study. These results would afford new possibilities in carbon dioxide fixation chemistry.
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| Free Research Field |
有機合成化学
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