2014 Fiscal Year Final Research Report
Synthesis of unsaturated main group elements compounds and their application for activation of small molecules
| Project/Area Number |
24350031
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (B)
|
| Allocation Type | Partial Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Kinki University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
HASHIZUME Daisuke 独立行政法人理化学研究所, その他部局等, ユニットリーダー (00293126)
|
|---|
| Project Period (FY) |
2012-04-01 – 2015-03-31
|
| Keywords | 典型元素 / 不飽和結合 / ホウ素 / 水素化ホウ素化合物 / ジボラン / X線結晶構造解析 / ジホスフェン / リン |
|---|
| Outline of Final Research Achievements |
Novel unsaturated compounds of boron, silicon, phosphorus, etc. have been synthesized by the introduction of the fused-ring bulky "Rind" groups, which we have recently developed. Their molecular structures and chemical bonding have been elucidated by the experimental and theoretical studies. We have also examined the reactivity of the resulting unsaturated main group elements compounds. Especially, we have focused on the synthesis of new hydroboron compounds, and their structures clearly confirmed by X-ray crystallography. The reactions of the dihydrodiborane(4) with small molecules such as dihydrogen and carbon monoxide have been investigated.
|
| Free Research Field |
無機化学
|
