Development and Applications of Molecular Transformation by Carbon-Carbon Bond Cleavage on Transition Metals

2014 Fiscal Year Final Research Report

• Project/Area Number: 24350043
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Hokkaido University
• Principal Investigator: TAKAHASHI Tamotsu 北海道大学, 触媒化学研究センター, 教授 (30163273)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Keywords: チタン錯体 / 反応機構 / カルベン / 炭素―炭素結合切断 / 炭素―炭素結合生成 / アゾベンゼン / インデン誘導体 / トリメチルホスフィン

Outline of Final Research Achievements

Creating environmentally-friendly chemical processes is nowadays a much attractive issue of ‘Sustainable Chemistry’. Our Laboratory conducts basic research of developing high efficient construction processes for various carbon skeletons. This includes developing novel synthetic methodologies based on a combination of carbon-carbon bond cleavage and formation reactions.
In this research, we found novel carbon-carbon bond cleavage reactions of Cp ligand on titanium. Furthermore, by use Cp ligand as building blocks, via a combination of carbon-carbon bond cleavage and formation reactions, a variety of molecular transformations were realized successfully.

Free Research Field

合成化学/有機化学反応/炭素多環化合物/有機金属化合物/機能材料/デバイス