2014 Fiscal Year Final Research Report
Development of Supramolecular Block Copolymers via Unique Molecular Recognition
| Project/Area Number |
24350060
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
HAINO Takeharu 広島大学, 理学(系)研究科(研究院), 教授 (80253053)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 超分子化学 / 分子認識 / 高分子化学 |
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| Outline of Final Research Achievements |
We developed a methodology that employed our unique host-guest motifs to achieve supramolecular block polymeric assemblies with a high degree of organization. The calix[5]arene-fullerene "ball-and-socket" interaction and molecular associations of bisresorcinarenes were demonstrated to be key intermolecular connections that facilitated supramolecular block copolymerization of monomeric building blocks. We also synthesized white-light-emitting graphene quantum dots via the peripheral functionalization as a new carbon-based functional material.
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| Free Research Field |
超分子化学
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