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2015 Fiscal Year Final Research Report

Design of metal complexes with organic ligand bearing photo-sensitive moieties and its application to catalytic transformations

Research Project

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Project/Area Number 24350068
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional materials chemistry
Research InstitutionOsaka University

Principal Investigator

Yasuda Makoto  大阪大学, 工学(系)研究科(研究院), 教授 (40273601)

Project Period (FY) 2012-04-01 – 2016-03-31
Keywords錯体 / 光反応 / 反応場 / ルイス酸 / 共役
Outline of Final Research Achievements

The boron compounds are abundant but less effective for catalyst. We have synthesized a new boron compounds with cage-shaped organic framework with photo-sensitive moieties. The newly synthesized cage-shaped boron compounds acted as a catalyst for some organic reactions. The selective reaction of aromatic compounds over aliphatic compounds was accomplished due to the pi-pocket moiety around the boron center in the complex. Introduction of benzofuran moiety into cage-shaped borate led to the photo-sensitive catalyst. In fact, irradiation of UV light to the reaction of silly enolate with aldehyde in the presence of the benzofuran-based catalyst made the increased catalytic activity. Irradiation of black-light also increased the yield of the product. The synthesized complexes were fully analyzed by X-ray crystallography and theoretical calculation.

Free Research Field

有機化学

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Published: 2017-05-10  

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