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2014 Fiscal Year Final Research Report

Preparation of Zeolite Nano-sized Crystals as Structured Active Sites and Highly Shape-selective Reaction Process with Them

Research Project

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Project/Area Number 24360325
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionHokkaido University

Principal Investigator

MASUDA Takao  北海道大学, 工学(系)研究科(研究院), 教授 (20165715)

Co-Investigator(Kenkyū-buntansha) TAGO Teruoki  北海道大学, 大学院工学研究院, 准教授 (20304743)
NAKASAKA Yuta  北海道大学, 大学院工学研究院, 助教 (30629548)
Project Period (FY) 2012-04-01 – 2015-03-31
Keywordsゼオライト / ナノ結晶 / フェリシリケート / ジメチルナフタレン / アルキル化 / 高圧液相反応 / ゼオライト膜 / 構造性活性点
Outline of Final Research Achievements

Nano-sized crystals of MFI, MOR, MTW and TON zeolites were successively synthesized. These crystals can be regarded as structured active sites with negligibly small resistance to mass transfer. Furthermore, these acidic properties were succeeded to be controlled by inserting Fe into their frameworks. MTW nano-sized crystal catalyst thus obtained showed high activity for methylation of 2-methyl-naphtalene. The deactivation of the catalyst could be remarkably prevented in liquid phase reaction under high pressures. MTW nano-sized crystal-layered catalyst membranes were successively prepared. The research on their application to the methylation is continuing, to confirm its validity.

Free Research Field

触媒反応工学

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Published: 2016-06-03  

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