2014 Fiscal Year Final Research Report
Application of Mechanochemical Reaction to the Synthesis of Novel Microporous Materials
| Project/Area Number |
24360335
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | The University of Kitakyushu |
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Principal Investigator |
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| Research Collaborator |
IKEDA Takuji 産業技術総合研究所, 化学プロセス研究部門, 主任研究員 (60371019)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 多孔質材料 / 新規構造 / ヘテロ配位 / ヘテロ金属 / アルカリ土類金属 / メカノケミカル / 吸着 |
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| Outline of Final Research Achievements |
A novel synthesis method for crystalline silicate materials was developed by applying mechanochemical reaction. By using this novel method to introduce alkaline earth metal species such as Ca and Sr into silicate framework, various unknown silicate materials were successfully synthesized. Some of their crystal structure were determined by X-ray structural analysis and proved to have unique micropore structures, which led to the selective adsorption of water or carbon dioxide molecules. This novel synthesis method can be applied to the synthesis of conventional zeolite materials. This method facilitated the synthesis of metallosilicate zeolites that were hardly synthesized by a conventional method and enabled the synthesis of a silicoaluminophosphate zeolite under a wide variety of conditions.
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| Free Research Field |
無機材料合成
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