Synthesis of Reactive Metal Complexes Bearing New Tripodal Ligand and Their Application to the Activation of Small Molecules

2014 Fiscal Year Final Research Report

• Project/Area Number: 24550039
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Gunma University
• Principal Investigator: TAKEDA Nobuhiro 群馬大学, 大学院理工学府, 准教授 (80304731)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Keywords: 三脚型四座配位子 / 遷移金属錯体 / チオエーテル配位子 / シリル配位子 / リン配位子 / 酸化反応 / ヒドロシリル化反応

Outline of Final Research Achievements

We synthesized dimethylpalladium complex, group 11 metal complexes and dichlororuthenium complex bearing a new tripodal tetradentate phosphine ligand, P[C6H4-2-S(i-Pr)]3 (1). Palladium and platinum complexes bearing a new tripodal tetradentate silyl ligand, －Si(C6H4-2-SR)3 (2), were also synthesized. Their structures and reactivities were elucidated and catalytic reactions of PhCH2CH2OH with HSiEt3 using [Ag2(1)2]2(ClO4) or [Au2(1)2]2(OTf), catalytic oxidation of and catalytic hydrosilylation of 4-phenyl-1-butene with HSi(OEt)3 using [PtCl(2)] were found.

Free Research Field

有機元素化学