2014 Fiscal Year Final Research Report
Synthesis and properties of multi-dimensional pi-conjugated compounds composed of highly integrated heteroaromatics such as carbazole
| Project/Area Number |
24550040
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KATO Shin-ichiro 群馬大学, 大学院理工学府, 助教 (70586792)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 複素環 / カルバゾール / チオフェン / 光物性 / π共役 / ドナー / シクロファン / ホスト |
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| Outline of Final Research Achievements |
Carbazole dimers and trimers were systematically synthesized, and the structure-property relationships, namely the effects of connecting positions and spacers on the properties were disclosed. Various oligomers composed of carbazole and thiophene were also systematically synthesized, and the effects of connecting positions and numbers of aromatics on the properties were elucidated.
Acyclic host compounds (molecular receptors) possessing ethynylcarbazole moieties at 1,8-positions of carbazole were systematically synthesized, and the complexation behavior with some acceptors was investigated. Conjugated macrocycles composed of carbazole and triazole moieties were successfully synthesized by click reactions, and their self-association and complexation with anions such as iodide ion were clarified.
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| Free Research Field |
構造有機化学
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