Synthesis and Properties of Electron-deficient Aluminum Cluster Compounds Based on Bottom-up Approach

2014 Fiscal Year Final Research Report

• Project/Area Number: 24550048
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Kyoto University
• Principal Investigator: AGOU Tomohiro 京都大学, 化学研究所, 助教 (90466798)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Keywords: アルミニウム / 有機典型元素化学 / 有機金属化学 / 分子活性化 / 低配位化学種

Outline of Final Research Achievements

We have synthesized barrelene-type organoaluminum compounds bearing an Al-Al single bond and elucidated their reactivities as synthetic equivalents of highly reactive Al=Al doubly-bonded species. Reactions of the barrelene-type organoaluminum compounds with unsaturated compounds as well as transition metal complexes afforded the corresponding electron-deficient organoaluminum species and complexes bearing aluminum-transition metal bonds.

Free Research Field

有機典型元素化学