2014 Fiscal Year Final Research Report
Development of strongly luminescent copper(I) and silver(I) complexes by hybridization
Project/Area Number |
24550072
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | University of Toyama |
Principal Investigator |
TSUGE Kiyoshi 富山大学, 大学院理工学研究部(理学), 教授 (60280583)
|
Co-Investigator(Renkei-kenkyūsha) |
NOZAKI Koichi 富山大学, 大学院理工学研究部(理学), 教授 (20212128)
|
Project Period (FY) |
2012-04-01 – 2015-03-31
|
Keywords | 発光性 / 銅 / 銀 / チオラト錯体 / 複合化 / エネルギー移動 |
Outline of Final Research Achievements |
Luminescent transition metal complexes have been explored not only as the photosensitizers but also as the luminescent materials for light emitting diodes because of their phosphorescence and because the feasible control over the luminescent properties, molecular size, and solubility by applied ligands. In this research, a series of novel luminescent copper complexes having thiophenol derivatives was prepared. The photophysical measurements clarified that their luminescent properties are strongly affected by the coexisting pyridyl ligands. The research upon the luminescent copper halogeno coordination polymers reveals that the mixed-ligand coordination polymers work as antenna system with the specific combination of bridging ligands.
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Free Research Field |
錯体化学
|