2014 Fiscal Year Final Research Report
Syntheses and Spin Dynamics of Mixed-valent Heterometallic One-dimensional Chains
| Project/Area Number |
24550074
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gifu University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 一次元鎖 / 多核錯体 / 金属結合 / 混合原子価 / スピン |
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| Outline of Final Research Achievements |
In order to obtain mixed-valent platinum and ruthenium one-dimensional chains containing redox-active ligands, platinum and ruthenium dinuclear complexes have been synthesized from amidate-hanging platinum mononuclear complexes. It was succeeded in introducing dioxolene ligands into amidate-bridged platinum and rhodium dinuclear complexes. It was also succeeded in obtaining ten kinds of novel one-dimensional chains formed by unbridged platinum and rhodium bonds, where four of them show paramagnetic.
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| Free Research Field |
金属錯体化学
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