2014 Fiscal Year Final Research Report
Development and application of linear linking methods of multinucleaer complexes
| Project/Area Number |
24550084
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Chuo University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | クラスター / シアナミド / 高次構造化 / ルテニウム / パラジウム |
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| Outline of Final Research Achievements |
Cyanamide ions are soft and sterically less demanding anions and act as versatile bridging ligands with a variety of coordination modes. This study aimed at development of novel cluster core expansion reactions of cyanamido-bridged small clusters to construct clusters with three-dimensional higher-order structures. The novel findings obtained in this study include (1) core expansion reaction of dinuclear ruthenium complex by linking terminal nitrogen atoms of cyanamido ligands, (2) observation of reversible coordination mode change between N,N- and N,N'-cyanamido ligands, and (3) cluster core transformation reactions from a tetranuclear palladium complex to tri- and pentanuclear clusters.
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| Free Research Field |
有機金属化学、錯体化学
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