2014 Fiscal Year Final Research Report
Development of functional system of syndiotactic polystyrene with organometallic compounds
Project/Area Number |
24550249
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Polymer/Textile materials
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Research Institution | Shizuoka University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
SAWATARI Chie 静岡大学, 教育学部, 教授 (70196319)
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Project Period (FY) |
2012-04-01 – 2015-03-31
|
Keywords | 高分子構造・物性 / シンジオタクチックポリスチレン / ゲスト分子 / 共結晶 / 配向結晶化 / 偏光蛍光回転角度分布法 / 広角エックス線回折 / シリカナノ粒子 |
Outline of Final Research Achievements |
First we clarified that guest organic molecules co-crystallized with syndiotactic polystyrene (SPS) were able to react with chemical species in a solvent including water. By reacting guest molecules clathrated in SPS crystalline phases, we have obtained some special SPS films such as films coated with silver through silver-mirror reaction or SPS co-crystalline films with organometallic compounds such as pyridine-copper chloride or pyridine-copper bromide. Moreover, we have developed the preparation method of SPS epsilon crystalline phase with high purity. Finally we have succeeded to orientate polymers having electrical conductivity such as polyaniline along with cavities of SPS epsilon crystalline phase.
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Free Research Field |
機能性高分子
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