2014 Fiscal Year Final Research Report
Development of Catalytic, Asymmetric One-Electron Transfer Reactions Using Triarylamine- and Arylsulfide-Based Organocatalysts
| Project/Area Number |
24590031
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Meiji Pharmaceutical University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 不斉芳香族第三アミン / 一電子移動 / 有機触媒 / 陽極酸化 / 光電子移動 / 可視光型増感剤 / ポルフィリン / ビナフチルアミン |
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| Outline of Final Research Achievements |
A challenge for developing triarylamine- and arylsulfide-based organocatalysts that can mediate asymmetric, one-electron transfer reactions of various organic molecules, such as alcohols and ethers is described. Among triarylamine and arylsulfide derivatives examined, triarylamines bearing chiral biaryl moieties were found to be a possible effective ‘asymmetric, one-electron transfer catalyst,’ which could mediate asymmetric oxidation of benzylethers via anodic processes. In addition to these studies, synthesis and physical properties of new porphyrin derivatives, which could be used as an efficient photosensitizer, were also explored.
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| Free Research Field |
化学系薬学（物理有機化学）
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