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2013 Fiscal Year Final Research Report

Development of innovative automobile exhaust gas purifying catalyst by solvothermal reaction

Research Project

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Project/Area Number 24651068
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionTohoku University

Principal Investigator

SATO Tsugio  東北大学, 多元物質科学研究所, 教授 (90091694)

Co-Investigator(Kenkyū-buntansha) YIN Shu  東北大学, 多元物質科学研究所, 准教授 (40271994)
Project Period (FY) 2012-04-01 – 2014-03-31
Keywordsセリア / 固溶体 / 形態制御 / 自動車排ガス浄化 / 三元触媒 / 酸化スズ / 酸素吸蔵能 / 耐熱性
Research Abstract

Calcium or tin doped ceria-zirconia nanoparticles, which showed the thermal stability and oxygen storage capacity superior to ceria-zirconia alloy, were fabricated by solvothermal reaction. The composites of calcium or tin doped ceria-zirconia nanoparticles, gamma alumina and palladium showed the excellent performance as a automobile exhaust gas purifying catalyst.
It was also found that tin oxide possesses the oxygen storage capacity like ceria, and that the strontium and barium doped tin oxide nanoparticles fabricated by solvothermal reaction showed the thermal stability and oxygen storage capacity superior to ceria-zirconia alloy.

  • Research Products

    (37 results)

All 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results) Presentation (29 results) Remarks (1 results)

  • [Journal Article] Aluminium Doped Ceria-Zirconia Supported Palladium-Alumina Catalyst with High Oxygen Storage Capacity and CO Oxidation Activity2013

    • Author(s)
      Qiang Dong, Shu Yin, Chongshen Guo, Xiaoyong Wu, Takeshi Kimura, Tsugio Sato
    • Journal Title

      Mater. Res. Bull.

      Volume: 48 Pages: 4989-4992

    • Peer Reviewed
  • [Journal Article] Cobalt Doped Ceria-Zirconia Supported Paradium-Alumina Catalyst with High Oxygen Storage Capacity for CO Oxidation2013

    • Author(s)
      Qiang Dong, Shu Yin, Chongshen Guo, Xiaoyong Wu, Takeshi Kimura, Thihang Le, Taro Sakanakura, Tsugio Sato
    • Journal Title

      Materials Science and Engineering

      Volume: 47, 012065 Pages: 1-6

  • [Journal Article] Solution Synthesis of Homogeneous Plate-like Multifunctional CeO_2 Particles2012

    • Author(s)
      Shu Yin, Y. Minamidate, Shunsuke Tonouchi, Takashi Goto, Qiang Dong, Hisayosi Yamane, Tsugio Sato
    • Journal Title

      RSC Advance

      Volume: 2 Pages: 5976-5982

    • Peer Reviewed
  • [Journal Article] A New Oxygen Storage Capacity Material of a Tin-doped Ceria-Zirconia- Supported Paradium-Alumina Catalyst with High CO Oxidation Activity2012

    • Author(s)
      Qian Dong, Shu Yin, Chongshen Guo, Tsugio Sato
    • Journal Title

      Chem. Lett

      Volume: 41(10) Pages: 1250-1252

    • Peer Reviewed
  • [Journal Article] Aluminum-doped ceria-zirconia solid solutions with enhanced thermal stability and high oxygen storage capacity2012

    • Author(s)
      Qian Dong, Shu Yin, Chongshen Guo, Tsugio Sato
    • Journal Title

      Nanoscale Research Letters

      Volume: 7, 542 Pages: 1-8

    • Peer Reviewed
  • [Journal Article] Hydrothermal synthesis of tin doped ceria-zirconia solid solutions with enhanced thermal stability and oxygen storage capacity2012

    • Author(s)
      Qiang Dong, Shu Yin, Chongshen Guo, Takeshi Kimura, Tsugio Sato
    • Journal Title

      RSC Advances

      Volume: 2 Pages: 12770-12774

    • Peer Reviewed
  • [Journal Article] Ce_<0.5>Zn_<0.4>Sn_<0.1>O_2/Al_2O_3 Catalysis with Enhanced Oxygen Storage Capacity and High CO Oxidation Ability2012

    • Author(s)
      Qian Dong, Shu Yin, Chongshen Guo, Tsugio Sato
    • Journal Title

      Catal. Sci. Technol.

      Volume: 2 Pages: 2521-2524

    • Peer Reviewed
  • [Presentation] ソルボサーマル反応による環境調和材料の創製2014

    • Author(s)
      佐藤次雄
    • Organizer
      公益社団法人日本セラミックス協会2014年年会資源・環境関連材料部会部会特別講演
    • Place of Presentation
      横浜
    • Year and Date
      2014-03-18
  • [Presentation] セリア基金属酸化物の形態制御とその酸素貯蔵能2014

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      公益社団法人日本セラミックス協会2014年年会
    • Place of Presentation
      横浜
    • Year and Date
      2014-03-18
  • [Presentation] ソルボサーマル反応による新規自動車排ガス浄化触媒の開発2014

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      第4回東北大学新機能無機物質探索研究センターシンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      2014-02-10
  • [Presentation] 新規酸素貯蔵材料とその自動車三元触媒活性2014

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      第4期東北大学研究所連携プロジェクト平成25年度成果報告会プログラム『ヒューマンサイエンス&テクノロジー』
    • Place of Presentation
      仙台
    • Year and Date
      2014-02-05
  • [Presentation] Novel Oxygen Storage Materials and Their Automotive Three-way Catalytic Application, Sixth French Research Organizations2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      Tohoku University Joint Workshop on Frontier Materials
    • Place of Presentation
      仙台
    • Year and Date
      2013-12-03
  • [Presentation] Solvothermal Synthesis of Ceria Based Metal Oxides for Automotive Catalysts2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      Tenth International Conference on Flow Dynamics
    • Place of Presentation
      仙台
    • Year and Date
      2013-11-26
  • [Presentation] 高い酸素ストレージ能をもつCeO2-Mn3O4複合金属酸化物の合成とその触媒活性2013

    • Author(s)
      董強、肴倉太郎、殷シュウ、佐藤次雄
    • Organizer
      無機マテリアル学会第127回講演会
    • Place of Presentation
      米沢
    • Year and Date
      2013-11-14
  • [Presentation] Alkaline Earth Metal lons Doped M-SnO2 (M=Mg, Ca, Sr, Ba) : Novel Oxygen Storage Materials and Automotive Three-way Catalytic Application2013

    • Author(s)
      Qiang Dong, Shu Yin, Miura Akira, Takei Takahiro, Kumada Nobuhiro, Tsugio Sato
    • Organizer
      International Symposium on Inorganic and Environmental Materials 2013
    • Place of Presentation
      Rennes, France
    • Year and Date
      2013-10-30
  • [Presentation] スズドープしたセリア-ジルコニアの三元触媒の作製とその自動車排ガス浄化機能2013

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      平成25年度日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      長岡
    • Year and Date
      2013-10-24
  • [Presentation] Novel Oxygen Storage Materials and Their Automotive Three-way Catalytic Application2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      仙台
    • Year and Date
      2013-09-30
  • [Presentation] Control of Chemical Composition and Morphology of Ceria for Enviromental Cleanup and Human Health2013

    • Author(s)
      Qiang Dong, Shu Yin, Takehiro Goto, Tsugio Sato
    • Organizer
      The International Conference on Nanoscience and Technology, China 2013
    • Place of Presentation
      Beijing, Chin
    • Year and Date
      2013-09-06
  • [Presentation] カルシウムをドープしたセリア-ジルコニアの酸素貯蔵能と自動車排ガス浄化機能2013

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      無機マテリアル学会第126回学術講演会
    • Place of Presentation
      船橋
    • Year and Date
      2013-06-07
  • [Presentation] ソルボサーマル反応場でのセラミックスナノ・マイクロ形態制御と高機能発現2013

    • Author(s)
      佐藤次雄、殷シュウ
    • Organizer
      日本金属学会2013年春期(第152回)講演大会
    • Place of Presentation
      東京
    • Year and Date
      2013-03-27
  • [Presentation] CeO2-Mn3O4複合金属酸化物の酸素貯蔵能と触媒活性2013

    • Author(s)
      董強、肴倉太郎、殷シュウ、佐藤次雄
    • Organizer
      公益社団法人日本セラミックス協会2013年年会
    • Place of Presentation
      東京
    • Year and Date
      2013-03-18
  • [Presentation] 汎用元素を用いた新規酸素貯蔵/放出材料の合成とその自動車三元触媒への応用2013

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      第2回新機能無機物質探索研究センターシンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      2013-02-26
  • [Presentation] セリア基複合金属酸化物のOSC評価と自動車排ガス浄化機能2013

    • Author(s)
      肴倉太郎、董強、殷シュウ、佐藤次雄
    • Organizer
      第51回セラミックス基礎科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2013-01-10
  • [Presentation] Calcium-doped ceria- zirconia solid solutions with enhanced oxygen storage capacity for automobile three-way catalytic application2013

    • Author(s)
      Qiang Dong, Thi Hang Le, Taro Sakanakura, Hasan Mehdi, Shu Yin, Tsugio Sato
    • Organizer
      第51回セラミックス基礎科学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2013-01-10
  • [Presentation] バリウムをドープした酸化スズの自動車三元触媒への応用2012

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      平成24年度日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      盛岡
    • Year and Date
      2012-11-08
  • [Presentation] Preparation and Characterization of CeO2-ZrO2-MxOy (M=Sn, Al) Solid Solutions for the Three-way Catalytic Application2012

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      2^<nd> International Conference on Competitive Materials and Technology Processes
    • Place of Presentation
      Miskolc-Lillafured, Hungary
    • Year and Date
      2012-10-12
  • [Presentation] Control of the Oxygen Storage Capacity of Ceria for Enviromental Cleanup and Human Health2012

    • Author(s)
      Tsugio Sato, Qiang Dong, Shu Yin
    • Organizer
      2^<nd> International Conference on Competitive Materials and Technology Processes
    • Place of Presentation
      Miskolc-Lillafured, Hungary
    • Year and Date
      2012-10-12
  • [Presentation] High oxygen storage capacity and CO oxidation activity of tin doped ceria-zirconia catalysts supported on alumina2012

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      公益社団法人日本セラミックス協会第25回秋季シンポジウ
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-20
  • [Presentation] スズをドープしたセリアージルコニア固溶体の自動車三元触媒への応用2012

    • Author(s)
      董強、殷シュウ、難波哲哉、小渕存、佐藤次雄
    • Organizer
      平成24年度化学系学協会東北大会
    • Place of Presentation
      秋田
    • Year and Date
      2012-09-16
  • [Presentation] Fabrication of Ceria-based Mixed Metal Oxides with Excellent Oxygen Storage Capacity and Thermal Stability for Environmental Cleanup2012

    • Author(s)
      Tsugio Sato, Qiang Dong, Shu Yin
    • Organizer
      International Conference on Traditional and Advanced Ceramics
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      2012-08-23
  • [Presentation] Solvothermal Synthesis of Ceria-based Metal Oxides with Excellent Oxygen Storage Capacity and Thermal Stability2012

    • Author(s)
      Tsugio Sato, Qiang Dong, Shu Yin
    • Organizer
      CJK2012 Urumuqi conference
    • Place of Presentation
      Urumuqi, China
    • Year and Date
      2012-08-17
  • [Presentation] ソルボサーマル反応によるセラミックスナノ粒子の合成と環境調和機能2012

    • Author(s)
      佐藤次雄、殷シュウ
    • Organizer
      日本ゾル-ゲル学会第10回討論会
    • Place of Presentation
      横浜
    • Year and Date
      2012-07-27
  • [Presentation] Solvothermal Synthesis and Oxygen Storage Capacity of Ce and Zr-based Mixed Oxide Nanoparticles2012

    • Author(s)
      Tsugio Sato, Qiang Dong, Shu Yin
    • Organizer
      4^<th> International Congress on Ceramics
    • Place of Presentation
      Chicago, USA
    • Year and Date
      2012-07-17
  • [Presentation] Preparation and characterization of CeO2-ZrO2-SnO2 solid solutions for catalytic applications2012

    • Author(s)
      董強、殷シュウ、佐藤次雄
    • Organizer
      無機マテリアル学会第124回学術講演会
    • Place of Presentation
      船橋
    • Year and Date
      2012-06-08
  • [Presentation] Preparation of Ce0.5ZrxSn0.5-xO2 solid solutions with enhanced oxygen storage capacity for catalytic application via a facile solvothermal route2012

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      14^<th> International Association of Colloid and Interface Scientists
    • Place of Presentation
      仙台
    • Year and Date
      2012-05-18
  • [Presentation] 吸入曝露したセリウムとユーロピウムの肺内動態と骨への移行2012

    • Author(s)
      篠原厚子、松川岳久、熊坂利夫、佐藤次雄、千葉百子、横山和仁
    • Organizer
      日本希土類学会第29回希土類討論会
    • Place of Presentation
      札幌
    • Year and Date
      2012-05-15
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/center/CENIM/field_eimc.html

URL: 

Published: 2015-06-25  

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