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2013 Fiscal Year Final Research Report

Development of removal method of radioactive Sr and Cs by silicic acid from nutrient rice

Research Project

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Project/Area Number 24651072
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionTokyo University of Marine Science and Technology

Principal Investigator

TAKAHASHI Miho (田中 美穂)  東京海洋大学, 海洋科学技術研究科, 准教授 (30236640)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywordsケイ酸 / 錯形成 / ストロンチウム / セシウム
Research Abstract

137Cs and 90Sr are present on the surface of the ground due to fallout. The chemistry of fixing Cs to soil and dissolution of Sr into water was examined. I studied the possibility of a safe method for the removal of Sr and Cs from soil, and the complexation of Sr and Cs at molecular level.Sr2+ was recovered 100% from soil, which is originally contained in soil. Cs was attached to soil by any solution, such as water, silicic acid, citric, ascorbic, or standard solution of mold. Cs was extracted almost 5-6% from soil by water, organic acids and aluminum nitrate. However, Cs was extracted less than 1.5% with silicic acid. There was almost no complexation of Cs with silicic acid, whereas Sr complexes were observed. This complex was bidentate and imigrates through soil as its silicate form. It is considered that Cs promotes the dissolution of silica gel to form large particles and Cs acts as a catalyst in the hydrolysis of silica gel.

  • Research Products

    (32 results)

All 2014 2013 2012 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (20 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] CE-ESI-MS/CE-ICP-MSによる溶液中のアルミニウムのスペシエーション2014

    • Author(s)
      中本大輔,田中美穂
    • Journal Title

      分析化学

      Volume: 63(5) Pages: 383-390

    • Peer Reviewed
  • [Journal Article] Letter to Editor : Concerning the comments "Silicon Species in Seawater" by Professor Exley and Professor Sjoberg2014

    • Author(s)
      Miho Tanaka, Kazuya Takahashi, Masao Nemoto and Naho Horimoto
    • Journal Title

      Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy

      Volume: 117 Pages: 822

    • Peer Reviewed
  • [Journal Article] イヌにおけるシリカ結石の誘発因子と予防2013

    • Author(s)
      田崎由実,伊藤源太,三浦直樹,田中美穂,桃井康行
    • Journal Title

      日本ペット栄養学会誌

      Volume: 16(2) Pages: 61-66

    • Peer Reviewed
  • [Journal Article] ESI-MSを用いた鉄(III)のスペシエーション : 加水分解と有機配位子の錯形成2013

    • Author(s)
      卜部達也,田中美穂
    • Journal Title

      材料とプロセス(CAMP-ISIJ)

      Volume: 26 Pages: 660-661

    • Peer Reviewed
  • [Journal Article] Ionized silica in the estuary of a river as supply to seawater : identification and ionization efficiency of silica species by FAB-MS2013

    • Author(s)
      Miho Tanaka and Kazuya Takahashi
    • Journal Title

      Estuarine, Coastal and Shelf Science

      Volume: 1-7 Pages: 121-122

    • Peer Reviewed
  • [Journal Article] Determination Method of Multi Elements in Ferromanganese Samples by LA-ICP-MS2013

    • Author(s)
      Junichi Hirata, Kazuya Takahashi, and Miho Tanaka
    • Journal Title

      Anal. Sci

      Volume: 29 Pages: 151-155

    • Peer Reviewed
  • [Journal Article] Selectivity of silica species in ocean observed from seasonal and local changes2013

    • Author(s)
      Miho Tanaka, Kazuya Takahashi, Masao Nemoto and Naho Horimoto
    • Journal Title

      Spectrochimica Acta Part A : Molecular and Biomolecular Spectroscopy

      Volume: 104(3) Pages: 423-429

    • Peer Reviewed
  • [Journal Article] ESI-MSによるモリブデン青法における錯体生成反応の解析2012

    • Author(s)
      高橋茉莉子,田中美穂
    • Journal Title

      分析化学

      Volume: 61(12) Pages: 1049-1054

    • Peer Reviewed
  • [Journal Article] 海洋への製鋼スラグからのケイ酸の溶出挙動

    • Author(s)
      田中美穂,平田純一,中本大輔,寺田愛,龍前以緒,高橋茉莉子,生川智啓,高橋和也,相本道宏
    • Journal Title

      鉄と鋼

      Volume: (印刷中)

    • Peer Reviewed
  • [Journal Article] レーザーアブレーション/ICP-MSによるマンガン団塊の年輪構造に含有する微量元素の局所定量分析

    • Author(s)
      平田純一,田中美穂
    • Journal Title

      分析化学

      Volume: (印刷中)

    • Peer Reviewed
  • [Journal Article] ESI-MSによる溶液中のチタンの同定と酸化挙動の評価

    • Author(s)
      龍前以緒,田中美穂
    • Journal Title

      分析化学

      Volume: (印刷中)

    • Peer Reviewed
  • [Presentation] Cesium Fixing to soil by silicic acid2013

    • Author(s)
      Miho Tanaka and Kazuya Takahashi
    • Organizer
      International Society for Trace Element Research in Humans
    • Place of Presentation
      Keio Plaza Hotel Tokyo, Shinjyuku, Tokyo
    • Year and Date
      20131118-22
  • [Presentation] ESI-MSを用いた鉄(III)のスペシエーション : 加水分解と有機配位子の錯形成2013

    • Author(s)
      卜部達也,田中美穂
    • Organizer
      日本鉄鋼協会第166回秋季講演大会
    • Place of Presentation
      金沢大学(金沢)
    • Year and Date
      20130917-19
  • [Presentation] 福井県沖の表面海水のケイ酸の分布と季節変動2013

    • Author(s)
      田中美穂,高橋和也,高垣守,鮎川航太,宮田克士,金田充
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20130910-12
  • [Presentation] ESI-MSを用いたケイ酸と2価の遷移金属の錯形成に関する評価2013

    • Author(s)
      有我洋香,中本大輔,平田純一,田中美穂
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      20130910-12
  • [Presentation] Observation of large hydrolytic aluminum polyoxocation (Al26 and A130) using electrospray ionization mass spectrometry2013

    • Author(s)
      Tatsuya Urabe and Miho Tanaka
    • Organizer
      33rd International Conference on Solution Chemistry
    • Place of Presentation
      Kyoto Terrsa, Kyoto, Japan
    • Year and Date
      20130707-12
  • [Presentation] Removement of Sr from Soil Using Silicic Acid Solution2013

    • Author(s)
      Miho Tanaka, Kazuya Takahashi
    • Organizer
      5th International FESTEM Symposium on Trace Elements and Minerals
    • Place of Presentation
      Avignon, France
    • Year and Date
      20130522-24
  • [Presentation] Speciation of Aluminum-Fluoride Complexs in solution2013

    • Author(s)
      Daisuke Nakamoto, Tatsuya Urabe, Miho Tanaka
    • Organizer
      5th International FESTEM Symposium on Trace Elements and Minerals
    • Place of Presentation
      Avignon, France
    • Year and Date
      20130522-24
  • [Presentation] 90-Srに含まれる土壌からの環境にやさしい除去方法の開発2013

    • Author(s)
      田中美穂,高橋和也,寺田愛,平田純一
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      函館北大水産
    • Year and Date
      20130518-19
  • [Presentation] ESI-MSによるアンチモンを用いたモリブデン青法の反応経路の解析2013

    • Author(s)
      高橋茉莉子,有我洋香,田中美穂
    • Organizer
      第73回分析化学討論会
    • Place of Presentation
      函館北大水産
    • Year and Date
      20130518-19
  • [Presentation] 河川から海洋におけるケイ酸の循環と化学種2013

    • Author(s)
      田中美穂
    • Organizer
      日本分析化学会環境分析研究懇談会平成25年度第2回講演会
    • Place of Presentation
      東京海洋大学
    • Year and Date
      2013-11-21
  • [Presentation] 海水への有機酸や塩を用いたスラグからの鉄とシリカの溶出モデル2013

    • Author(s)
      寺田愛,相本道宏,田中美穂
    • Organizer
      日本鉄鋼協会第165回春季講演大会第37回学生ポスターセッション
    • Place of Presentation
      東京電機大(東京)
    • Year and Date
      2013-03-28
  • [Presentation] 水圏への鉄・シリカ溶出に対するスラグ炭酸化処理の影響2013

    • Author(s)
      中本大輔,相本道宏,田中美穂
    • Organizer
      日本鉄鋼協会第165回春季講演大会第37回学生ポスターセッション
    • Place of Presentation
      東京電機大(東京)
    • Year and Date
      2013-03-28
  • [Presentation] シリカ化学種からみた黄砂の海水への役割(展望とトピックスに選出された)2012

    • Author(s)
      田中美穂,高橋和也
    • Organizer
      日本分析化学会第61年会
    • Place of Presentation
      金沢大学(金沢)
    • Year and Date
      20120919-21
  • [Presentation] The difference between the measurement of FAB-MS and ESI-MS on silica speciation dissolved in pure water and its application2012

    • Author(s)
      Miho Tanaka, kazuya Takahashi, Mariko Takahashi
    • Organizer
      61th ASMS Conference on Mass Spectrometry and Allied Topics
    • Place of Presentation
      Vancouver Convention Centre, Vancouver, BC, Canada
    • Year and Date
      20120520-24
  • [Presentation] The Yellow sand and Seawater Interaction in the Point of Silica Speciationi2012

    • Author(s)
      Miho Tanaka, Kazuya Takahashi
    • Organizer
      19th International Mass Spectrometry Conference
    • Place of Presentation
      Kyoto
    • Year and Date
      20120000
  • [Presentation] Study on Reaction Process of the Complexation of Silicomolybdic and Phosphomolybdic Acids by ESI-MS2012

    • Author(s)
      Mariko Takahashi, Miho Tanaka
    • Organizer
      19th International Mass Spectrometry Conference
    • Place of Presentation
      Kyoto
    • Year and Date
      20120000
  • [Presentation] The Development of Analytical Method for Speciation of Transition Metal Ions in Seawater by CE-ESI-MS2012

    • Author(s)
      Daisuke Nakamoto, Masashi Wakasugi, Miho Tanaka
    • Organizer
      19th International Mass Spectrometry Conference
    • Place of Presentation
      Kyoto
    • Year and Date
      20120000
  • [Presentation] シリカの存在状態別分析;シリカの構造と金属との錯形成2012

    • Author(s)
      田中美穂,高橋和也,高橋茉莉子
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2012-05-19
  • [Presentation] ESI-MSを用いたアルミニウム化学種の形態別分析2012

    • Author(s)
      卜部達也,田中美穂
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2012-05-19
  • [Presentation] CE-ESI-MSによる2価および3価の遷移金属イオンの相互分離と溶存状態分析に関わる高濃度NaClの効果2012

    • Author(s)
      中本大輔,田中美穂,若杉将史
    • Organizer
      第72回分析化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2012-05-19
    • Invited
  • [Remarks] 研究のガイドラインなど

    • URL

      http://www2.kaiyodai.acjp/~mihotnk/

URL: 

Published: 2015-06-25   Modified: 2015-07-14  

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