2013 Fiscal Year Final Research Report
Development of ambipolar organic semiconductor using properties of antiaromatic ring
| Project/Area Number |
24655036
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
NISHINAGA Tohru 首都大学東京, 理工学研究科, 准教授 (30281108)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | 反芳香族性 / 有機半導体 / トランジスタ |
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| Research Abstract |
It is difficult to realize an ambipolar organic semiconductor with high and balanced mobility and only a few example of such semiconductors have been reported. In this work, unlike the conventional donor-acceptor structure, we succeeded in the development of a novel ambipolar semiconductor based on cyclic tetrathiophene having narrow HOMO-LUMO gap derived from antiaromatic planar COT ring.
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Research Products
(34 results)
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[Journal Article] Multifunctionalπ-Expanded Macrocyclic Oligothiophene 6-Mers and Related Macrocyclic Oligomers2014
Author(s)
Masahiko Iyoda, Keita Tanaka, Hideyuki Shimizu, Masashi Hasegawa, Tohru Nishinaga, Tomohiko Nishiuchi, Yoshihito Kunugi, Takayuki Ishida, Hiroyuki Otani, Hiroyasu Sato, Koji Inukai, Kazukuni Tahara, Yoshito Tobe
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Journal Title
J. Am. Chem. Soc.
Volume: 136
Pages: 2389-2396
DOI
Peer Reviewed
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