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2013 Fiscal Year Final Research Report

Development of multichromic device based on the dynamic molecular motion of the chiral metal complexes

Research Project

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Project/Area Number 24655053
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionOsaka City University

Principal Investigator

MIYAKE Hiroyuki  大阪市立大学, 大学院理学研究科, 准教授 (00271198)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywordsセンシング / 超分子化学 / 不斉 / 発光 / 円二色性 / 赤外振動スペクトル / 希土類錯体 / スイッチング
Research Abstract

Metal complexes have unique spectroscopic and magnetic properties depending on their characteristic coordination geometries. To develop the rapid conversion system of their properties in solution for multichromic transmission and detection, we developed (1) the multi-luminescent device in response to the external stimuli, (2) the multichromic system including conversion of coordination geometries, (3) the multi-detectable system for determination of the substrates' chirality, which have been constructed from the labile and chiral metal complexes developed by our group.

  • Research Products

    (30 results)

All 2014 2013 2012 Other

All Journal Article (6 results) Presentation (21 results) (of which Invited: 11 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Lanthanide Tris(β-diketonates) as Useful Probes for Chirality Determination of Biological Amino Alcohols in Vibrational Circular Dichroism : Ligand to Ligand Chirality Transfer in Lanthanide Coordination Sphere2014

    • Author(s)
      H. Miyake, K. Terada and H. Tsukube
    • Journal Title

      Chirality

      Volume: 26 Pages: 293-299

    • DOI

      10.1002/chir.22319

  • [Journal Article] 分子認識から始まる動的分子プログラミング–錯体化学を基盤としたキラリティー誘起と反転スイッチング2013

    • Author(s)
      三宅弘之
    • Journal Title

      化学

      Volume: 68 (5) Pages: 46-52

    • URL

      http://www.kagakudojin.co.jp/kagaku/web-kagaku03/c6805/c6805-miyake/index.html

  • [Journal Article] M aterials-Based Receptors : Design Principle and Applications2013

    • Author(s)
      K. Singh, D. Sareen, P. Kaur, H. Miyake, and H. Tsukube
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Pages: 6914-6936

    • DOI

      10.1002/chem.201300249

  • [Journal Article] Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis (2-pyridylmethyl)amine Ligands toward Separation Application2012

    • Author(s)
      M. Yano, H. Takemoto, M. Tatsumi, H. Miyake, H. Tsukube
    • Journal Title

      Bull. Chem. Soc. Jp.

      Volume: 85 Pages: 490-496

    • DOI

      10.1246/bcsj.20110281

  • [Journal Article] Helicity Inversion from Left- to Right- Handed Square Planar Pd(II) Complexes : Synthesis of a Diastereomer Pair from a Single Chiral Ligand and their Structure Dynamism2012

    • Author(s)
      H. Miyake, M. Ueda, S. Murota, H. Sugimoto, H. Tsukube
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 3721-3723

    • DOI

      10.1039/C2CC18154A

  • [Journal Article] Coordination Chemistry Strategies for Dynamic Helicates : Time-Programmable Chirality Switching with Labile and Inert Metal Helicates2012

    • Author(s)
      H. Miyake, and H. Tsukube
    • Journal Title

      Chem. Soc. Rev.

      Volume: 41 Pages: 6977-6991

    • DOI

      10.1039/C2CS35192G

  • [Presentation] TPEN-Nd(III)錯体を用いたキラリティープローブ法の開発2014

    • Author(s)
      國屋拓郎・篠田哲史・築部浩・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      20140327-30
    • Invited
  • [Presentation] キラルメタロフォルダマーの合成とらせん構造の制御2014

    • Author(s)
      藤田愛子・篠田哲史・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      20140327-30
    • Invited
  • [Presentation] 硝酸アニオンをトリガーとしたトリス(2,2'-ビピリジン)金属錯体のヘリシティー反転とタイムプログラミング2014

    • Author(s)
      阪本達哉・小原一朗・山口健太郎・築部浩・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      20140327-30
    • Invited
  • [Presentation] テトラアミドサイクレン―希土類錯体の新規合成法の開発2014

    • Author(s)
      佐竹良介・篠田哲史・築部浩・三宅弘之
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      20140327-30
    • Invited
  • [Presentation] Time-Programming of Conformational Dynamics in Chiral Metallopeptides2014

    • Author(s)
      H. Miyake
    • Organizer
      The 2nd International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      Campus Plaza Kyoto, Kyoto, Japan
    • Year and Date
      20140111-12
  • [Presentation] Stimuli-responsive molecular motion in optically active metal complexes2013

    • Author(s)
      H. Miyake
    • Organizer
      246th ACS National Meeting & Exposition
    • Place of Presentation
      Indianapolis, IN, USA
    • Year and Date
      20130908-12
  • [Presentation] Chirality Induction and Its Dynamic Control in Coordination Chemistry2013

    • Author(s)
      H. Miyake
    • Organizer
      Symmetry Festival
    • Place of Presentation
      Delft, The Netherlands
    • Year and Date
      20130802-07
    • Invited
  • [Presentation] NO ^–3 Responsive Helicity Inversion of Tris(2,2'-bipyridine)-Labile Metal Complexes : Dynamic Chirality Integration from Helical Complex Terminal to Complex Center2013

    • Author(s)
      H. Miyake, T. Sakamoto, K. Ohara, K. Yamaguchi, H. Tsukube
    • Organizer
      14th International Conference on Chiroptical Spectroscopy
    • Place of Presentation
      Nashville, Tennessee
    • Year and Date
      20130609-13
  • [Presentation] 錯体ヘリシティーの反転スイッチング;錯体から錯体へのキラル情報の伝達2013

    • Author(s)
      三宅弘之・阪本達哉・小原一朗・山口健太郎・築部浩
    • Organizer
      第10回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      和歌山大学
    • Year and Date
      20130525-26
  • [Presentation] 配位化学を活用したキラル分子プログラミング2013

    • Author(s)
      三宅弘之
    • Organizer
      第20回記念シンポジウムモレキュラー・キラリティー2013
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      20130510-11
    • Invited
  • [Presentation] Stimuli-Responsive Dynamic Molecular Motion in Labile Metal Complexes2013

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Center for Nanoscience
    • Place of Presentation
      Dept. of Chemistry & Biochemistry, University of Missouri - St. Louis, USA
    • Year and Date
      2013-09-06
    • Invited
  • [Presentation] Stimuli-Responsive Dynamic Molecular Motions in Chiral Metal Complexes2012

    • Author(s)
      H. Miyake and H. Tsukube
    • Organizer
      International Conference on Emerging Advanced Nanomaterials 2012 (ICEAN-2012)
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      20121022-25
    • Invited
  • [Presentation] Helicity Switching Of Dynamic Metal Complexes Toward Supramolecular Synthesis2012

    • Author(s)
      H. Miyake^, and H. Tsukube
    • Organizer
      IUPAC 8th International Conference on Novel Materials and their Synthesis (NMS-VIII) & 22^<nd> International Symposium on Fine Chemistry and Functional Polymers (FCFP-XXII)
    • Place of Presentation
      Xi'An, P. R. China
    • Year and Date
      20121014-19
    • Invited
  • [Presentation] Microwave Assisted Direct Syntheses of Optically Active Metal Complexes with Kinetically Inert Metal Centers2012

    • Author(s)
      H. Miyake, M. Ueda, S. Murota, H. Sugimoto, H. Tsukube
    • Organizer
      62^<nd> JSCC Symposium
    • Place of Presentation
      Toyama
    • Year and Date
      20120921-23
  • [Presentation] Enantioselective binding characteristics of amino acid to chiral copper(II) complex using electrospray ionization mass spectrometry coupling with the deuterium-labeled method2012

    • Author(s)
      T. Nakakoji, H. Sato, H. Miyake, H. Kawasaki, R. Arakawa, D. Ono, H. Tsukube, M. Shizuma
    • Organizer
      19th International Mass Spectrometry Conference (IMSC2012)
    • Place of Presentation
      Kyoto International Conference Center, Kyoto, Japan
    • Year and Date
      20120915-21
  • [Presentation] Helicity Inversion in a Square Planar Pd(II) Complex2012

    • Author(s)
      H. Miyake and H. Tsukube
    • Organizer
      The 24th International Symposium on Chirality (Chirality 2012)
    • Place of Presentation
      Fort Worth, Texas, USA
    • Year and Date
      20120610-13
  • [Presentation] Dendrimeric Array of Chiral Metal Complexes : Chirality Integration and Dynamic Inversion2012

    • Author(s)
      H. Miyake, T. Sakamoto, K. Ohara, K. Yamaguchi, H. Tsukube
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Centennial Hall Kyushu University School of Medicine, Fukuoka, Japan
    • Year and Date
      20120517-18
  • [Presentation] Synthesis of a Diastereomer Pair of Square Planar Palladium(II) Complex and its Helicity Inversion2012

    • Author(s)
      H. Miyake, M. Ueda, S. Murota, H. Tsukube
    • Organizer
      Symposium on Molecular Chirality ASIA 2012
    • Place of Presentation
      Centennial Hall Kyushu University School of Medicine, Fukuoka, Japan
    • Year and Date
      20120517-18
  • [Presentation] キラルな錯体を活用した動的分子スイッチの開発~キラル情報の伝達・増幅・変換2012

    • Author(s)
      三宅弘之
    • Organizer
      錯体化学若手の会近畿地区勉強会
    • Place of Presentation
      大学利用施設UNITY、神戸
    • Year and Date
      2012-12-08
  • [Presentation] Coordination Chemistry-Based Approach for Dynamic Helicates2012

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry
    • Place of Presentation
      Faculty of Science, Chulalongkorn University, THAILAND
    • Year and Date
      2012-10-25
    • Invited
  • [Presentation] Molecular Programming of Helicity Inversion in Coordination Chemistry2012

    • Author(s)
      H. Miyake
    • Organizer
      Department Seminar, Department of Chemistry
    • Place of Presentation
      Wayne State University, USA
    • Year and Date
      2012-06-08
    • Invited
  • [Book] Synergy in Supramolecular Chemistry, (ed) T. Nabeshima, Supramolecular chemistry strategies for naked-eye detection and sensing2014

    • Author(s)
      K. Singh, P. Kaur, H. Miyake and H. Tsukube
    • Total Pages
      400
    • Publisher
      CRC Press
  • [Book] 無機化学演習-大学院入試問題を中心に(化学演習シリーズ7)2012

    • Author(s)
      中沢浩、西岡孝訓、篠田哲史、廣津昌和、三宅弘之(板崎真澄共著、中沢浩編)
    • Total Pages
      215
    • Publisher
      東京化学同人
  • [Remarks]

    • URL

      http://www.sci.osaka-cu.ac.jp/chem/func/FC/Top.html

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Published: 2015-06-25  

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