2012 Fiscal Year Final Research Report
Control of C-H activation by proximal metal-ligand interaction and its application to selective transformation reaction of saturated hydrocarbons
| Project/Area Number |
24655081
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
TAKESHI Naota 大阪大学, 大学院・基礎工学研究科, 教授 (20164113)
|
|---|
| Project Period (FY) |
2012
|
| Keywords | 渡環型錯体 / 金属水素相互作用 / 分子内C-H活性化 |
|---|
| Research Abstract |
Transition metal complexes with “picnic basket” shaped structures bearing bridged polymethylene unit were prepared. Regioselective intramolecular CH-metal (d orbital) interaction was observed. Remote controlling of the position of C-H activation can be performed by tuning of methylene spacer length and the structure of ligands.
|
Research Products
(24 results)
