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2013 Fiscal Year Final Research Report

Construction of organic optical switching device by using light driven reversible aggregation conversion

Research Project

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Project/Area Number 24655124
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionOsaka University

Principal Investigator

TOHNAI NORIMITSU  大阪大学, 工学(系)研究科(研究院), 准教授 (30346184)

Co-Investigator(Renkei-kenkyūsha) HISAKI Ichiro  大阪大学, 大学院工学研究科, 助教 (90419466)
Project Period (FY) 2012-04-01 – 2014-03-31
Keywords結晶工学 / 光スイッチング / フォトクロミック / 有機塩 / 超分子複合体
Research Abstract

Tuning the optical properties of luminscent materials by external stimuli has been intensively studied because of their ability for various devices, such as sensors and optical media. However, practical example of changing optical properties by light stimuli is challenging. In this context, we prepared organic crystals from anthracenedisulfonic acids and photochromic thymine arranges and reversibly modulate optical properties by UV irradiation. The organic salt can incorporate several organic solvents and emits various fluorescence depending on guest solvents.

  • Research Products

    (18 results)

All 2014 2013 2012 Other 0

All Journal Article (10 results) Presentation (7 results) (of which Invited: 2 results) Remarks (1 results)

  • [Journal Article] Water inclusion as a trigger for modulation of anthracene arrangement and fluorescence emission of organic salt2014

    • Author(s)
      M. Sugino, K. Hatanaka, T. Miyano, I. Hisaki, M. Miyata, A. Sakon, H. Uekusa, N. Tohnai
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Pages: 732

    • DOI

      10.1016/j.tetlet.2013.12.005

  • [Journal Article] Amphiphilic Inclusion Spaces for Various Guests and Regulation of Fluorescence Intensity of 1,8-Bis(4-aminophenyl)anthracene Crystals2014

    • Author(s)
      M. Sugino, K. Hatanaka, Y. Araki, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Chem. - Eur. J.

      Volume: 20 Pages: 3069

    • DOI

      10.1002/chem.201304541

  • [Journal Article] Engineering Switchable Rotors in Molecular Crystals with Open Porosity2014

    • Author(s)
      A. Comotti, S. Bracco, A. Yamamoto, M. Beretta, T. Hirukawa, N. Tohnai, M. Miyata, P. Sozzani
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Pages: 618

    • DOI

      10.1021/ja411233p

  • [Journal Article] Role-Allocated Combination of Two Types of Hydrogen Bonds towards Constructing a Breathing Diamondoid Porous Organic Salt2013

    • Author(s)
      A. Yamamoto, T. Hasegawa, T. Hamada, T. Hirukawa, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Chem. Eur. J.

      Volume: 19 Pages: 3006

    • DOI

      10.1002/chem.201202959

  • [Journal Article] Dynamically Deformable Cube-like Hydrogen-Bonding Networks in Water-Responsive Diamondoid Porous Organic Salts2013

    • Author(s)
      A. Yamamoto, T. Hamada, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 52 Pages: 1709

    • DOI

      10.1002/anie.201208153

  • [Journal Article] A facile and versatile approach to efficient enhancement of solid-state luminescence by organic-inorganic hybrid salts2013

    • Author(s)
      N. Tohnai, M. Sugino, Y. Araki, K. Hatanaka, I. Hisaki, M. Miyata
    • Journal Title

      Dalton Trans.

      Volume: 42 Pages: 15922

    • DOI

      10.1039/c3dt51422f

  • [Journal Article] Elucidation of Anthracene Arrangement for Excimer Emission at Ambient Conditions2013

    • Author(s)
      M. Sugino, Y. Araki, K. Hatanaka, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Cryst. Growth Des.

      Volume: 13 Pages: 4986

    • DOI

      10.1021/cg401166v

  • [Journal Article] Diamondoid Porous Organic Salts toward Applicable Strategy for Construction of Versatile Porous Structures2012

    • Author(s)
      A. Yamamoto, S. Uehara, T. Hamada, M. Miyata, I. Hisaki, N. Tohnai
    • Journal Title

      Cryst. Growth Des.

      Volume: 12 Pages: 4600

    • DOI

      10.1021/cg300796u

  • [Journal Article] Supramolecular-tilt-chirality on twofold helical assemblies2012

    • Author(s)
      I. Hisaki, T. Sasaki, N. Tohnai, M. Miyata
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Pages: 10066

    • DOI

      10.1002/chem.201200688

  • [Journal Article] Regulation of pi-Stacked Anthracene Arrangement for Fluorescence Modulation of Organic Solid from Monomer to Excited Oligomer Emission2012

    • Author(s)
      T. Hinoue, Y. Shigenoi, M. Sugino, Y. Mizobe, I. Hisaki, M. Miyata, N. Tohnai
    • Journal Title

      Chem. Eur. J.

      Volume: 18 Pages: 4634

    • DOI

      10.1002/chem.201103518

  • [Presentation] 有機塩を用いた超分子的アプローチによる結晶構造制御と機能化2013

    • Author(s)
      藤内謙光
    • Organizer
      第17回液晶化学研究会シンポジウム
    • Place of Presentation
      筑波
    • Year and Date
      2013-06-13
  • [Presentation] 水素結合ネットワークを利用した多孔質有機塩(POSs)の構築とそのゲスト依存的発光特性2013

    • Author(s)
      浜田智也・山本淳志・藤内謙光・久木一朗・宮田幹二
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都
    • Year and Date
      2013-05-29
  • [Presentation] 有機結晶のフォトルミネッセンスとその制御2013

    • Author(s)
      藤内謙光
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      草津
    • Year and Date
      2013-03-25
    • Invited
  • [Presentation] Supramolecular Assemblies and Fluorescence Properties of 9,10-Anthracene Derivative in Inclusion Crystals2012

    • Author(s)
      N. Tohna, I. Hisaki, M. Miyata
    • Organizer
      Japan-Taiwan Bilateral Workshop on Nano-Science 2012
    • Place of Presentation
      Suita, Osaka、Japan
    • Year and Date
      2012-12-04
    • Invited
  • [Presentation] Supramolecular assemblies and photophysical properties of9,10-anthracene derivative in solid state2012

    • Author(s)
      N. TOHNAI, M. SUGINO I. HISAKI, M. MIYATA
    • Organizer
      第61回高分子年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2012-05-29
  • [Presentation] πスタック型ナノクラスターからなるビーズ状超分子の構築と外部刺激応答的固体発光2012

    • Author(s)
      藤内謙光・樋上友亮・久木一朗・宮田幹二
    • Organizer
      第9回ホスト・ゲスト化学シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2012-05-26
  • [Presentation] Fluorescence Tuning System by using Organic Salts composed Anthracene Disulfonic Acid (ADS) and Primary Alkyl Amines in Crystalline State0

    • Author(s)
      N. Tohnai, I. Hisaki, M. Miyata
    • Organizer
      XXIV IUPAC Photochemistry
    • Place of Presentation
      Coimbra,Portugal
    • Year and Date
      00000715
  • [Remarks]

    • URL

      http://www.mls.eng.osaka-u.ac.jp/~mol_rec/

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Published: 2015-06-25  

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