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2013 Fiscal Year Final Research Report

Development of in situ soft X-ray absorption spectroscoy for analysis of ceramics materials in high temperature devices

Research Project

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Project/Area Number 24656374
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

AMEZAWA Koji  東北大学, 多元物質科学研究所, 教授 (90263136)

Co-Investigator(Kenkyū-buntansha) YASHIRO Keiji  東北大学, 大学院環境科学研究科, 准教授 (20323107)
HASHIMOTO Shin-ichi  東北大学, 大学院工学研究科, 准教授 (60598473)
Project Period (FY) 2012-04-01 – 2014-03-31
Keywords軟X線吸収分光 / その場測定 / 機能性酸化物 / 電子構造
Research Abstract

In this work, in situ soft X-ray absorption spectroscopic technique, which can be used to analyze electronic structures of functionalized oxides under controlled atmosphere, temperature and polarization, was established. By applying the differential evacuation system for ambient pressure soft x-ray spectrocopy togehter with the specific sample holder developed in this work, in situ soft X-ray absroption spectroscopic measurements were made possible at high temperature while controlling atmosphere under polarization. Through measurements with LaCoO3 and La2NiO4 as model oxides, it was found that absorption spectra could be clearly obtained below 873 K of temperature and 0.01 bar of oxygen partial pressure.The established in situ analytical technique can be a powerful and versatile tool for the direct observation of electronic structures of functionalized oxides used for high temperature devices.

  • Research Products

    (21 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (16 results) (of which Invited: 5 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Electronic Structures of LaCoO_3-Based Oxides Studied by Soft X-Ray Absorption Spectroscopy under Controlled Temperatures and Oxygen Partial Pressures2013

    • Author(s)
      R. Oike, K. Amezawa, Y. Tamenori, K. Yashiro, T. Nakamura, T. Kawada
    • Journal Title

      Electrochemical Society Transactions

      Volume: 57(1) Pages: 2051-2056

    • DOI

      10.1149/05701.2051ecst

    • Peer Reviewed
  • [Journal Article] Development of in situ soft X-ray absorption spectroscopic technique under high temperature and controlled atmosphere

    • Author(s)
      R. Oike, K. Amezawa, T. Nakamura, Y. Tamenori, K. Yashiro, T. Kawada
    • Journal Title

      Solid State Ionics

      Volume: (in press)

    • Peer Reviewed
  • [Presentation] その場軟X線吸収分光測定によるランタンニッケル酸化物緻密膜電極の電子状態の評価2014

    • Author(s)
      大池諒,為則雄祐,藤巻義信,中村崇司,八代圭司,川田達也,雨澤浩史
    • Organizer
      2014年電気化学会第81回大会
    • Place of Presentation
      大阪
    • Year and Date
      20140329-31
  • [Presentation] In Situ Analysis of Solid State Ionics Devices2013

    • Author(s)
      K. Amezawa, T. Nakamura
    • Organizer
      Sixth French Research Organizations -Tohoku University Joint Workshop on Frontier Matrials (FRONTIER 2013)
    • Place of Presentation
      Sendai
    • Year and Date
      20131201-05
  • [Presentation] In Situ Analysis of Materials and Reactions in Solid Oxide Fuel Cells2013

    • Author(s)
      K. Amezawa, T. Nakamura, K. Yashiro, T. Kawada, Y. Orikasa, Y. Uchimoto
    • Organizer
      First International Symposium on Innovative Energy Research
    • Place of Presentation
      Sendai
    • Year and Date
      20131125-26
    • Invited
  • [Presentation] 軟X線吸収分光を用いた固体酸化物形燃料電池材料のその場分析2013

    • Author(s)
      大池諒,雨澤浩史,為則雄祐,八代圭司,中村崇司,川田達也
    • Organizer
      第39回固体イオニクス討論会
    • Place of Presentation
      熊本
    • Year and Date
      20131120-22
  • [Presentation] In situ analysis of materials for solid oxide fuel cells by X-ray absorption spectroscopy2013

    • Author(s)
      K. Amezawa
    • Organizer
      2013 Composites at Lake Louise
    • Place of Presentation
      Lake Louise, Canada
    • Year and Date
      20131103-07
    • Invited
  • [Presentation] Electrochemical Oxygen Reduction Reaction on an Oxide Ion Conductor Investigated2013

    • Author(s)
      K. Amezawa, Y. Fujimaki, R. Oike, Y. Orikasa, T. Ina, T. Nakamura, K. Yashiro, Y. Uchimoto, T. Kawada
    • Organizer
      Situ X-ray Absorption Spectroscopy
    • Place of Presentation
      Montreal, Canada
    • Year and Date
      20131027-31
    • Invited
  • [Presentation] Electronic Structures of LaCoO_3-Based Oxides Studied by Soft X-Ray Absorption Spectroscopy under Controlled Temperatures and Oxygen Partial Pressures2013

    • Author(s)
      R. Oike, K. Amezawa, Y. Tamenori, K. Yashiro, T. Nakamura, T. Kawada
    • Organizer
      13th International Symposium on Solid Oxide Fuel Cells (SOFC-XIII)
    • Place of Presentation
      Ginowan
    • Year and Date
      20131006-11
  • [Presentation] 高温雰囲気制御軟X線吸収分光測定によるLa_2NiO_<4+>δ緻密薄膜電極の電子状態評価2013

    • Author(s)
      大池諒,雨澤浩史,為則雄祐,八代圭司,中村崇司,川田達也
    • Organizer
      第9回固体イオニクスセミナー
    • Place of Presentation
      下呂
    • Year and Date
      20130908-10
  • [Presentation] XAFSを用いた固体酸化物型燃料電池材料・反応のin situ解析2013

    • Author(s)
      雨澤浩史
    • Organizer
      薄膜・表面物理セミナー
    • Place of Presentation
      東京
    • Year and Date
      20130806-07
  • [Presentation] Electronic structures of sofc oxide cathodes studied by in situ soft x-ray absroption spectroscopy2013

    • Author(s)
      K. Amezawa, R. Oike, Y. Tamenori, K. Yashiro, T. Nakamura, T. Kawada
    • Organizer
      The 19th International Conference on Solid State Ionics
    • Place of Presentation
      Kyoto
    • Year and Date
      20130602-07
  • [Presentation] Overview of our research activities related to fuel cell and hydrogen technologies2013

    • Author(s)
      K. Amezawa
    • Organizer
      Workshop on Hydrogen French Embassy
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-05-08
    • Invited
  • [Presentation] 高温・雰囲気制御下での軟X線吸収分光測定技術の開発2013

    • Author(s)
      大池諒,為則雄祐,藤巻義信,中村崇司,八代圭司,川田達也,雨澤浩史
    • Organizer
      固体化学の新しい指針を探る研究会第74回定例研究会「若手研究者による研究発表会」
    • Place of Presentation
      東京
    • Year and Date
      2013-03-12
  • [Presentation] 高温・制御雰囲気下における軟エックス線吸収分光測定技術の開発2012

    • Author(s)
      雨澤浩史,為則雄祐,大池諒,八代圭司,中村崇司,川田達也
    • Organizer
      第38回固体イオニクス討論会
    • Place of Presentation
      京都
    • Year and Date
      20121203-05
  • [Presentation] in situ測定が切り拓く高温電気化学の新展開2012

    • Author(s)
      雨澤浩史
    • Organizer
      平成24年度化学系学協会東北大会
    • Place of Presentation
      秋田
    • Year and Date
      20120915-16
    • Invited
  • [Presentation] 高温制御雰囲気下でのin situ X線吸収分光測定2012

    • Author(s)
      雨澤浩史,八代圭司,中村崇司
    • Organizer
      平成24年度新エネルギー材料・デバイスプロジェクトグループ研究会
    • Place of Presentation
      福岡
    • Year and Date
      2012-10-30
  • [Presentation] 放射光を利用した高温作動型燃料電池のその場計測2012

    • Author(s)
      雨澤浩史
    • Organizer
      九州シンクロトロン光研究センター・東北大学多元物質科学研究所合同シンポジウム第6回九州シンクロトロン光研究センター研究成果報告会
    • Place of Presentation
      仙台
    • Year and Date
      2012-07-30
  • [Book] 「SPring-8の高輝度放射光を利用したグリーンエネルギー分野における電池材料開発」,"in-situ XAFS測定による固体酸化物形燃料電池の電極反応機構解析2014

    • Author(s)
      雨澤浩史
    • Total Pages
      252-259
    • Publisher
      CMC出版
  • [Book] 「in-situ測定/その場観察実例集~各種計測技術の実践テクニックおよび材料・デバイス別分析例~」,"1章4節:XAFS(X線吸収微細構造)によるin situ測定法とポイント2013

    • Author(s)
      雨澤浩史
    • Total Pages
      35-41, 265-270
    • Publisher
      情報機構
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/labo/amezawa/research-j.html

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Published: 2015-06-25   Modified: 2015-07-08  

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