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2013 Fiscal Year Final Research Report

Formation of porous surface on NiTi and suppression of Ni ion release

Research Project

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Project/Area Number 24656430
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Material processing/treatments
Research InstitutionTohoku University

Principal Investigator

UEDA Kyosuke  東北大学, 工学(系)研究科(研究院), 助教 (40507901)

Co-Investigator(Renkei-kenkyūsha) NARUSHIMA Takayuki  東北大学, 大学院工学研究科, 教授 (20198394)
KATO Hidemi  東北大学, 金属材料研究所, 准教授 (80323096)
Project Period (FY) 2012-04-01 – 2014-03-31
Keywordsニッケルチタン / ポーラス / アナターゼ / イオン溶出 / 表面改質 / 光触媒 / 水接触角 / 傾斜機能
Research Abstract

A dealloying Ni surface having a porous structure was prepared from NiTi alloys through immersion in molten metals. The concentration of Ni from the NiTi substrate to the surface was decreased in a stepwise manner forming an inner Ti2Ni layer and outer alpha-Ti layer on the substrate. The amounts of metallic ions eluted from these specimens to 1mass% lactic acid solution were evaluated. Despite the increased surface area of the dealloyed specimen, Ni ion elution was suppressed to the same level as that in the non-treated NiTi substrate. The anatase layer formed by two-step thermal oxidation suppressed the Ni ion release from the dealloyed substrate.

  • Research Products

    (11 results)

All 2014 2013 2012

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (7 results) Book (1 results)

  • [Journal Article] セラミックスコーティングによる金属系バイオマテリアル表面の高機能化2013

    • Author(s)
      成島 尚之, 上田 恭介, 佐渡 翔太
    • Journal Title

      機能材料

      Volume: 33(9) Pages: 33–39

    • Peer Reviewed
  • [Journal Article] Formation of anatase on commercially pure Ti by two-step thermal oxidation using N_2-CO gas2013

    • Author(s)
      N. Umetsu, S. Sado, K. Ueda, K. Tajima and T. Narushima
    • Journal Title

      Mater. Trans

      Volume: 54 Pages: 1302–1307

    • DOI

      10.2320/matertrans.ME201315

    • Peer Reviewed
  • [Journal Article] β-grain refinement ofα+β-type Ti-4.5Al-6Nb-2Fe-2Ml alloy by using rare-earth-oxide precipitates2013

    • Author(s)
      K. Ueda, S. Nakaoka, and T. Narushima
    • Journal Title

      Mater. Trans

      Volume: 54 Pages: 161–168

    • DOI

      10.2320/matertrans.ME201207

    • Peer Reviewed
  • [Presentation] Photocatalytic evaluation of anatase layer formed on Ti alloys by thermal oxidation2013

    • Author(s)
      S. Sado, K. Ueda, T. Narushima, M. Kawano, K. Ogasawara
    • Organizer
      International Symposium on Eco Topia Science 2013
    • Place of Presentation
      名古屋大学, 名古屋
    • Year and Date
      2013-12-14
  • [Presentation] 溶融金属浸漬法によるNiTi のポーラス表面形成とその応用2013

    • Author(s)
      上田恭介、廣橋正博、橋本龍真、和田武、加藤秀実、成島尚之
    • Organizer
      SMA シンポジウム2013
    • Place of Presentation
      ホテル華乃湯, 仙台
    • Year and Date
      2013-11-14
  • [Presentation] 二段階熱酸化法により作製したチタン上チタニア皮膜の評価2013

    • Author(s)
      佐渡 翔太、上田 恭介、成島 尚之
    • Organizer
      日本金属学会第153回大会(2013年秋期)
    • Place of Presentation
      金沢大学, 金沢
    • Year and Date
      2013-09-17
  • [Presentation] Dealloying of NiTi by immersion in metallic melt2013

    • Author(s)
      K. Ueda, M. Hirohashi, T. Narushima, T. Wada and H. Kato
    • Organizer
      The 8^<th> Pacific Rim International Conference on Advanced Materials and Processing (PRICM8)
    • Place of Presentation
      Hilton Waikoloa Village, Waikoloa, Hawaii, USA
    • Year and Date
      2013-08-09
  • [Presentation] 溶融金属浸漬法によるNiTi のポーラス化と金属イオン溶出2013

    • Author(s)
      上田 恭介、橋本 龍真、成島 尚之、和田 武、加藤 秀実
    • Organizer
      日本金属学会 第152回大会(2013年春期)
    • Place of Presentation
      東京理科大学, 東京
    • Year and Date
      2013-03-29
  • [Presentation] NiTi 合金中の非金属介在物2012

    • Author(s)
      上田 恭介、我妻由貴、青木翔、成島尚之、山下文祥、石川浩司
    • Organizer
      SMA シンポジウム2012
    • Place of Presentation
      神戸国際ビジネスセンター, 神戸
    • Year and Date
      2012-11-29
  • [Presentation] 溶融金属浸漬法によるNiTi からのNi 除去2012

    • Author(s)
      上田 恭介、廣橋 正博、成島 尚之、和田 武、加藤 秀実
    • Organizer
      日本金属学会第151回大会(2012年秋期)
    • Place of Presentation
      愛媛大学, 松山
    • Year and Date
      2012-09-18
  • [Book] Surface improvement for biocompatibility of biomedical Ti alloy by dealloying in metallic melt in Advances in Metallic Biomaterials Technology, Ed. by M. Niinomi, T. Narushima and M. Nakai.2014

    • Author(s)
      M. Hirohashi, K. Ueda, T. Wada, T.Narushima and H. Kato
    • Publisher
      Spriger-Verlag GmbH, Heidelberg (出版確定)

URL: 

Published: 2015-06-25  

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