2013 Fiscal Year Final Research Report
Development of Reaction Field for Converting Directly Polyalcohols to Allyl Compounds
| Project/Area Number |
24656477
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Reaction engineering/Process system
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| Research Institution | Hokkaido University |
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Principal Investigator |
MASUDA Takao 北海道大学, 工学(系)研究科(研究院), 教授 (20165715)
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| Co-Investigator(Kenkyū-buntansha) |
TAGO Teruoki 北海道大学, 大学院工学研究院, 准教授 (20304743)
NAKASAKA Yuta 北海道大学, 大学院工学研究院, 助教 (30629548)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | 反応工学 / 触媒・化学プロセス / バイオマス / 触媒設計 / 多価アルコール |
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| Research Abstract |
Main object of this research is to develop a catalytic reaction process to achieve direct allyl compounds synthesis from liner polyalcohols. Potassium supported iron oxide catalysis containing zirconia or alumina showed higher allyl alcohol yield from glycerol compared to the glycerol conversion over the iron oxide catalyst without potassium. In addition, it was clarified that polyalcohol conversion with formic acid, which is hydrogen donor, over the potassium supported iron oxide catalysis increase allyl compounds yield. Moreover, developed catalyst was effective for allyl alcohol formation from crude glycerol generated as a by-product in biodiesel production process.
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Research Products
(7 results)
