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2013 Fiscal Year Final Research Report

Nuclear coordinate dependence of electronic wave function studied by high-resolution electron momentum spectroscopy

Research Project

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Project/Area Number 24750004
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

YAMAZAKI MASAKAZU  東北大学, 多元物質科学研究所, 助教 (00533465)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywords電子状態 / 電子分光 / 電子衝突 / 分子軌道 / 波動関数
Research Abstract

In this study, in order to investigate correlation between nuclear and electron motions in a molecule, we have developed a high-resolution electron momentum spectroscopy that would be capable of measuring nuclear coordinate dependent electronic wave functions. As a result, the resolution of electron binding energy has been improved from 2.7 eV to 1.1 eV by improving energy resolution of an electron analyzer incorporated with a monochromatized incident electron beam. To achieve higher resolution, it is found to be fundamental to develop a new electron analyzer with reduced aberrations and advanced electron optics as well as to introduce highly stable voltage supplies.

  • Research Products

    (18 results)

All 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (10 results) Book (1 results) Remarks (1 results)

  • [Journal Article] 電子のオービタルパターンを見る2014

    • Author(s)
      山﨑優一
    • Journal Title

      パリティ

      Volume: 29巻 Pages: 13-15

    • URL

      http://pub.maruzen.co.jp/book_magazine/magazine/parity-back/parity2014/2014_01/1401_cont.html

  • [Journal Article] Development of an (e,2e) electron momentum spectroscopy apparatus using an ultrashort pulsed electron gun2013

    • Author(s)
      M. Yamazaki, Y. Kasai, K. Oishi, H. Nakazawa, M. Takahashi
    • Journal Title

      Rev. Sci. Instrum.

      Volume: Vol.84, 063105 Pages: 1-10

    • DOI

      10.1063/1.4809792

    • Peer Reviewed
  • [Journal Article] Interatomic resonant Auger effects in core-level photoemission from NO and CS_2 molecules2013

    • Author(s)
      M. Yamazaki, J. Adachi, T. Teramoto, A. Yagishita
    • Journal Title

      J. Phys. B

      Volume: Vol.46, 115101 Pages: 1-10

    • DOI

      10.1088/0953-4075/46/11/115101

    • Peer Reviewed
  • [Journal Article] Molecular-frame (e,2e) experiment for N_2 at large momentum transfer2013

    • Author(s)
      D. B. Jones, M. Yamazaki, N. Watanabe, M. Takahashi
    • Journal Title

      Phys. Rev. A

      Volume: Vol.87, 022714 Pages: 1-5

    • DOI

      10.1103/PhysRevA.87.022714

    • Peer Reviewed
  • [Journal Article] Electron-impact ionization of N_2 at large momentum transfer above the double-ionization threshold2012

    • Author(s)
      D. B. Jones, M. Yamazaki, N. Watanabe, M. Takahashi
    • Journal Title

      Phys. Rev. A

      Volume: Vol.86, 062707 Pages: 1-7

    • DOI

      10.1103/PhysRevA.86.062707

    • Peer Reviewed
  • [Journal Article] Vibrational effects on valence electron momentum distributions of ethylene2012

    • Author(s)
      N. Watanabe, M. Yamazaki, M. Takahashi
    • Journal Title

      J. Chem. Phys.

      Volume: Vol.137, 114301 Pages: 1-8

    • DOI

      10.1063/1.4752653

    • Peer Reviewed
  • [Presentation] 時間分解(e,2e)電子運動量分光の開発による化学反応におけるフロンティア電子運動の可視化2013

    • Author(s)
      山﨑優一, 髙橋正彦
    • Organizer
      原子衝突学会第38回年会
    • Place of Presentation
      埼玉
    • Year and Date
      2013-11-16
  • [Presentation] 時間分解電子運動量分光によるアセトンの光解離ダイナミクス2013

    • Author(s)
      山﨑優一, 大石慶也, 中澤博之, 葛西裕治, 髙橋正彦
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Year and Date
      2013-09-26
  • [Presentation] Development of time-resolved electron momentum spectroscopy : Preliminary results for the photodissociation dynamics of several molecules2013

    • Author(s)
      M. Yamazaki, M. Takahashi
    • Organizer
      International Symposium on (e,2e), Double Photo-ionization and Related Topics & 17th International Symposium on Polarization and Correlation in Electronic and Atomic Collisions
    • Place of Presentation
      中国・合肥市
    • Year and Date
      2013-08-01
  • [Presentation] Development of time-resolved electron momentum spectroscopy : a tool for visualizing the motion of electrons during a chemical reaction2013

    • Author(s)
      M. Yamazaki, Y. Kasai, K. Oishi, H. Nakazawa, M. Takahashi
    • Organizer
      XXVIII International Conference on Photonic, Electronic and Atomic Collisions
    • Place of Presentation
      中国・蘭州市
    • Year and Date
      2013-07-25
  • [Presentation] Development of time-resolved (e,2e) electron momentum spectroscopy : Preliminary results for the photodissociation dynamics of several molecules2013

    • Author(s)
      M. Yamazaki, Y. Kasai, K. Oishi, H. Nakazawa, M. Takahashi
    • Organizer
      29th Symposium on Chemical Kinetics and Dynamics
    • Place of Presentation
      仙台
    • Year and Date
      2013-06-06
  • [Presentation] 多次元電子分光による電子波動関数の立体特性に関する研究2013

    • Author(s)
      山﨑優一
    • Organizer
      日本物理学会第68回年次大会
    • Place of Presentation
      東広島
    • Year and Date
      2013-03-27
  • [Presentation] 時間分解電子運動量分光の開発 : 過渡状態電子運動の可視化へ向けて2012

    • Author(s)
      山﨑優一, 大石慶也, 葛西裕治, 川瀬裕也, 髙橋正彦
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-18
  • [Presentation] Progress towards development of time-resolved (e,2e) electron momentum spectroscopy2012

    • Author(s)
      M. Yamazaki, M. Takahashi
    • Organizer
      International Conference on Many Particle Spectroscopy of Atoms, Molecules, Clusters and Surfaces
    • Place of Presentation
      ドイツ・ベルリン
    • Year and Date
      2012-08-29
  • [Presentation] Progress towards development of time-resolved electron momentum spectroscopy2012

    • Author(s)
      M. Yamazaki, K. Oishi, Y. Kasai, Y. Kawase, M. Takahashi
    • Organizer
      2nd International Symposium on Electron Momentum Spectroscopy
    • Place of Presentation
      ベルギー・ブリュッセル
    • Year and Date
      2012-08-23
  • [Presentation] 時間分解(e,2e)電子運動量分光の開発2012

    • Author(s)
      山﨑優一, 大石慶也, 葛西裕治, 川瀬裕也, 髙橋正彦
    • Organizer
      原子衝突学会第37回年会
    • Place of Presentation
      東京
    • Year and Date
      2012-07-29
  • [Book] (e,2e) spectroscopy using fragmentation processes in"Fragmentation Processes (Topics in Atomic and Molecular Physics)"2013

    • Author(s)
      J. Lower, M. Yamazaki, M. Takahashi
    • Total Pages
      137-154
    • Publisher
      Cambridge University Press
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/modules/laboratory/index.php?laboid=42

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Published: 2015-06-25  

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