2014 Fiscal Year Final Research Report
Development of near-IR multiplex inverse Raman spectrometer and its application to elucidation of mechanism of photoconductivity
| Project/Area Number |
24750023
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Physical chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 時間分解分光 / 逆ラマン分光 / 近赤外分光 / 光電子移動 / 導電性高分子 |
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| Outline of Final Research Achievements |
We have developed a near-IR Raman spectrometer for observing structures of samples at molecular level without photodamage. The mechanism of energy dissipation from photoexcited beta-carotene has been revealed with the spectrometer. Stimulated Raman spectra of photoconductive polymers photoexcited with blue light have been recorded. The results strongly indicate that positively charged states are formed in the polymer in solutions. We have suggested the structure of the charged states and the mechanism of their formation from the peak position of the Raman signal and its time dependence.
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| Free Research Field |
物理化学，分子分光学
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