2015 Fiscal Year Final Research Report
Development of deuterium NMR spectroscopy of paramagnetic solids for simplification of spectral analysis
| Project/Area Number |
24750026
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Physical chemistry
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| Research Institution | Yamagata University (2013-2015)
Institute for Molecular Science (2012) |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2016-03-31
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| Keywords | 核磁気共鳴 / 固体 / 常磁性 / 重水素 |
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| Outline of Final Research Achievements |
Deuterium solid state NMR spectroscopy is an indispensable tool for investigating not only the static molecular structure but also dynamics with a time scale from nanoseconds to seconds. For paramagnetic solids, however, the analysis of measured NMR spectra may be difficult or impossible owing to a paramagnetic shift interaction. In the present work, we developed novel deuterium NMR methods to remove the paramagnetic effect from the spectrum, which enables us to obtain information about molecular structure and motions easily.
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| Free Research Field |
物理化学
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