2013 Fiscal Year Final Research Report
Development of Rare-Earth Catalyzed Regioselective Functionalization of C-H Bonds
| Project/Area Number |
24750046
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Institute of Physical and Chemical Research |
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Principal Investigator |
OYAMADA Juzo 独立行政法人理化学研究所, 環境資源科学研究センター, 特別研究員 (60525393)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | 希土類錯体 / C-H結合活性化 / アルキル化 / アニソール / アニリン |
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| Research Abstract |
Ortho-selective alkylation of anisoles has been achieved by use of cationic rare-earth alkyl complexes as catalysts. Similarly, 2-methylanisoles underwent ortho-selective benzylic alkylation. These catalysts could also be applied to ortho-selective alkyaltion of N,N-dialkylanilines, alkylation at a N-methyl group of N-methylamines and benzylic alkylation of methylbenzenes.
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