2013 Fiscal Year Final Research Report
Studies on structures, reactivity, and new synthetic route of silanone-coordinated transition metal complexes
| Project/Area Number |
24750053
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | シラノン錯体 / 合成 / 構造 / 反応性 / 不飽和結合性 / 分極 |
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| Research Abstract |
In this study, we investigated that structures and reactivity of the first silanone-coordinated transition metal complexes stabilized by coordination of Lewis base. We also tried development of a new route for synthesis of silanone-coordinated transition metal complexes. Reactions of silanone-coordinated complexes with polarized compounds afforded addition products to silicon-oxygen double bond. The results obtained from spectroscopic measurements and reactions with polarized compounds revealed that unsaturated character of the silicon-oxygen bond in silanone-coordinated transition metal complex.
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