2013 Fiscal Year Final Research Report
Synthesis of cyclic pi-conjugated molecules through the template synthetic approach and elucidation of their properties
| Project/Area Number |
24750087
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
YAMAGO Shigeru 京都大学, 化学研究所, 教授 (30222368)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | π共役系化合物 / 白金 / スズ / 金属交換反応 / 還元的脱離 / 単結晶構造解析 / 光物性 / 酸化還元特性 |
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| Research Abstract |
Curved pi-conjugated molecules with closed and three dimensional (3D) structures, such as fullerenes and carbon nanotube have been the subject of intensive research due to their potential applications in molecular electronics. However, basic molecular skeletons of 3D molecules are limited because of the lack of a rational and selective synthetic method by organic synthesis. We succeeded in the synthesis of 3D pi-conjugated molecule based on a new synthetic strategy, which involves the platinum-mediated assembly of pi-units by transmetallation and subsequent reductive elimination of the platinum.
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[Journal Article] Synthesis, Crystal Structure, and Physical Properties of a Ball-like Three-dimensional-Conjugated Compound2013
Author(s)
Kayahara E., Iwamoto T., Takaya H., Suzuki T., Fujitsuka M., Majima T., Yasuda N., Matsuyama N., Seki S., Yamago S.
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Journal Title
Nat. Commun.
Volume: 4
Pages: 2694-2700
DOI
Peer Reviewed
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