2013 Fiscal Year Final Research Report
Direct Chemical Modification of pi-Conjugated Polymers and their Electronic Properties
| Project/Area Number |
24750115
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Polymer chemistry
|
|---|
| Research Institution | Konan University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2012-04-01 – 2014-03-31
|
| Keywords | π共役高分子 / カルバゾール / 有機薄膜太陽電池 |
|---|
| Research Abstract |
Direct Friedel-Crafts acylation to the carbazole backbone on pi-conjugated polymer connecting at its 2,7-position was investigated. The acylation at 3,6-position of carbazole unit successfully occurred under the optimized reaction condition. Furthermore, novel pi-conjugated polymer for organic photovoltaic devices was synthesized by using the acylation method.
At the same time, new building blocks were investigated in order to achieve the control of the electronic state via direct chemical modification. As a result, the dehydration reaction between carbonyl unit and aniline derivative can be applied as a direct polymer functionalization method.
|
-
-
[Journal Article] In Situ KPFM Imaging of Local Photovoltaic Characteristics on Structured Organic Photovoltaic Devices2014
Author(s)
Watanabe, S.; Fukuchi, Y.; Fukasawa, M.; Sassa, T.; Kimoto, A.; Tajima, Y.; Uchiyama, M.; Yamashita, T.; Matsumoto, M.; Aoyama, T.
-
Journal Title
ACS Appl. Mater. Interfaces
Volume: 6
Pages: 1481-1487
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
