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2013 Fiscal Year Final Research Report

Development of zero-gap materials based on unsymmetrical metal complexes under ambient pressure

Research Project

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Project/Area Number 24750118
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionHokkaido University

Principal Investigator

KUBO Kazuya  北海道大学, 電子科学研究所, 助教 (90391937)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywords機能性材料 / 有機電子材料
Research Abstract

Zero-gap materials such as a graphene are intensively studied because of their potentials for development of new electric devices. However, synthesis and physical measurements of the thin film of graphene are difficult. The zero gap material based on the bulk compound is realized by applying pressure to an organic conductor. Dirac corn type electronic states are observed in the zero-gap materials. In this work, the electronic state of the organic conductor crystals based on unsymmetrical metal-dhithiolene complexes, exhibiting the Dirac corn like electronic state were investigated by crystal structures and their physical properties.

  • Research Products

    (26 results)

All 2014 2013 2012 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (18 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Design of Crystalline Spaces for Molecular Rotations in Crystals2014

    • Author(s)
      Zun-qi Liu, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Pages: 537-543

    • Peer Reviewed
  • [Journal Article] Crystal Structure and Physical Property of Dithiolene Complex Crystal with Adamantane Supramolecular Rotator2013

    • Author(s)
      Yin-Nan Yan, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Bulletin of Chemical Society of Japan

      Volume: 87 Pages: 417-419

    • Peer Reviewed
  • [Journal Article] Molecule-displacive ferroelectricity in organic supramolecular solids2013

    • Author(s)
      Heng-Yun Ye, Yi Zhang, Shin-ichiro Noro, Kazuya Kubo, Masashi Yoshitake, Zun-Qi Liu, Hong-Ling Cai, Da-Wei Fu, Hirofumi Yoshikawa, Kunio Awaga, Ren-Gen Xiong, Takayoshi Nakamura
    • Journal Title

      Scientific Reports

      Volume: 3, 2249 Pages: 6

    • Peer Reviewed
  • [Journal Article] Crystal Structure of a Supramolecular Cation Salt (adamantylammonium^+)2(benzo[18]crown- 6)2- [Pd(dmit)2]^<2->(acetone)22013

    • Author(s)
      Kazuya Kubo, Yin-Nan Yan, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Inorg. Chim. Acta

      Volume: 404 Pages: 206-209

    • Peer Reviewed
  • [Journal Article] (3-Fluoro-4-methoxyanilinium)^+([18]Crown -6) Supramolecular Cation Salt of Ferromagnetic [Mn^<II>Cr^<III>(oxalate)3]^−2013

    • Author(s)
      Toru Endo, Kazuya Kubo, Masashi Yoshitake, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Chem. Lett.

      Volume: 42 Pages: 137-139

    • Peer Reviewed
  • [Journal Article] Molecular motion in pyridazinium/crown ether supramolecular cation salts of a nickel dithiolene complex2013

    • Author(s)
      Zun-Qi Liu, Kazuya Kubo, Li Lin, Norihisa Hoshino, Shin-Ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Dalton trans.

      Volume: 42 Pages: 2930-2939

    • Peer Reviewed
  • [Presentation] 複数の水素結合部位を有する超分子カチオン結晶の構造と物性2014

    • Author(s)
      山田晃弘, 久保和也, 星野哲久, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-29
  • [Presentation] trans-anti-trans-dicyclohexano[18]crown -6/4-aminopyridinium超分子カチオンを導入した[Ni(dmit)_2]結晶の構造と誘電性2014

    • Author(s)
      渡辺大樹, 久保和也, 星野哲久, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-29
  • [Presentation] Crystal structure and physical properties of (4-aminopyridinium)(crown ether derivative) supramolecular cations in [Ni(dmit)_2] salts2014

    • Author(s)
      Ohshima Yu, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      The Sixth Hokkaido-Southeast University Bilateral Symposium on Material Science
    • Place of Presentation
      札幌
    • Year and Date
      2014-03-26
  • [Presentation] 結晶内分子回転により誘起される誘電応答に対する置換基効果2014

    • Author(s)
      中川翔太, 久保和也, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      日本化学会北海道支部会2014年冬季研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      2014-01-28
  • [Presentation] (4-aminopyridinium)(クラウンエーテル誘導体)超分子カチオンを有する[Ni(dmit)_2]塩の結晶構造と誘電性2014

    • Author(s)
      大島雄, 久保和也, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      化学系学協会北海道支部2014年冬季研究発表会
    • Place of Presentation
      札幌
    • Year and Date
      2014-01-28
  • [Presentation] Crystal structure and physical properties of (4-aminopyridinium)(crown ether derivative) supramolecular cations in [Ni(dmit)_2] salts2013

    • Author(s)
      Ohshima Yu, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      4th Asian Conference on Coordination Chemistry
    • Place of Presentation
      韓国
    • Year and Date
      2013-11-04
  • [Presentation] 超分子ローターを有する強磁性MnCr(oxalate) 3錯体結晶の構造と誘電物性2013

    • Author(s)
      吉竹理, 久保和也, 杉原寛之, 鈴木康孝, 川俣純, 芥川智行, 野呂真一郎, 中村貴義
    • Organizer
      錯体化学第63回討論会
    • Place of Presentation
      沖縄
    • Year and Date
      2013-11-02
  • [Presentation] アニリニウム/クラウンエーテル誘導体超分子カチオンとジチオレン錯体[Ni(dmit)_2]^<n-> (0 < n≦1)から構築される新規金属錯体結晶の構造と物性評価2013

    • Author(s)
      久保和也, 大島雄, 渡辺大樹, 山田晃弘, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      沖縄
    • Year and Date
      2013-11-02
  • [Presentation] Structure and Dielectric Properties of Protonated DABCO/[Ni(dmit)_2]^- Crystals2013

    • Author(s)
      Miyahara Masaki, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki and Nakamura Takayoshi
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      仙台
    • Year and Date
      2013-09-30
  • [Presentation] Structure and Adsorption Properties of Two-Dimensional Copper(II) Complexes with Methanesulfonate Anions2013

    • Author(s)
      Ishibashi Hidenori, Noro Shin-ichiro, Kubo Kazuya, Nakamura Takayoshi
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      仙台
    • Year and Date
      2013-09-30
  • [Presentation] (naphthalene-1-aminium)(dibenzo[18]crow n-6)[Ni(dmit)_2]結晶の構造と物性2013

    • Author(s)
      厳寅男, 芥川智行, 久保和也, 野呂真一郎, 中村貴義
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Year and Date
      2013-09-27
  • [Presentation] (m-halogenoanilium^+)(dibenzo[18]crown-6) [Ni(dmit)_2]^-結晶の構造と物性2013

    • Author(s)
      中川翔太, 久保和也, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      第7回分子科学討論会
    • Place of Presentation
      京都
    • Year and Date
      2013-09-24
  • [Presentation] Naphthalene-1-aminium–crown ether supramolecular cations in [Ni(dmit)_2] salts2013

    • Author(s)
      Yan Yin-Nan, Akutagwa Tomoyuki, Kubo Kazuya, Noro Shin-ichiro, Nakamura Takayoshi
    • Organizer
      11th International Conference on Materials Chemistry (MC11)
    • Place of Presentation
      イギリス
    • Year and Date
      2013-07-08
  • [Presentation] Supramolecuolar cations of (4-aminopyridinium)(dicyclohexano[18]cr own-6) in [Ni(dmit)_2] salt2013

    • Author(s)
      Ohshima Yu, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      11th International Conference on Materials Chemistry (MC11)
    • Place of Presentation
      イギリス
    • Year and Date
      2013-07-08
  • [Presentation] Structures and Physical Properties of Supramolecular Cation Salts (m-bromoanilinium^+)(crown ether derivative)[Ni(dmit)_2]^-2013

    • Author(s)
      Nakagawa Shota, Kubo Kazuya, Noro Shin-ichiro, Akutagawa Tomoyuki, Nakamura Takayoshi
    • Organizer
      11th International Conference on Materials Chemistry (MC11)
    • Place of Presentation
      イギリス
    • Year and Date
      2013-07-08
  • [Presentation] 有機アンモニウム系カチオン/クラウンエーテル誘導体からなる超分子カチオンをもつ[Pd(dmit)2]^<n-> (0< n < 2)アニオン塩の構造と物性2013

    • Author(s)
      久保和也, 厳寅男, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-25
  • [Presentation] 非対称金属ジチオレン錯体[(ppy or bpy)M(dithiolene)]n (M = Pt, Au; n = 0 or -1)による分子性導体構築とその物性評価2012

    • Author(s)
      久保和也, 川椙義高, 加藤礼三, 野呂真一郎, 中村貴義
    • Organizer
      錯体化学会第62回討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-22
  • [Presentation] (adamantylammonium)_2(benzo[18]crown-6)_2[ Pd(dmit)_2](acetone)_2の構造と物性2012

    • Author(s)
      久保和也, 厳寅男, 野呂真一郎, 芥川智行, 中村貴義
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-18
  • [Book] Conducting Single-Molecule Magnets(Handbook of Multifunctional Molecular Materials, Chapter 2)2013

    • Author(s)
      Kazuya Kubo, Hiroki Hiraga, Hitoshi Miyasaka, Masahiro Yamashita
    • Total Pages
      61-103 (全289ページ)
    • Publisher
      Pan Stanford Publishing
  • [Remarks]

    • URL

      http://org-com.es.hokudai.ac.jp/

URL: 

Published: 2015-06-25  

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