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2013 Fiscal Year Final Research Report

Development of high functional plasmonic nanostructures consisting of low-cost metal species

Research Project

  • PDF
Project/Area Number 24750135
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionNihon University

Principal Investigator

SUGAWA Kosuke  日本大学, 理工学部, 助教 (40580204)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywords表面プラズモン共鳴 / 金属ナノ構造 / 蛍光増強 / アルミニウム / 銅
Research Abstract

We investigated the properties of enhanced local electric fields generated on the nanostructures consisting of Cu cheaper than conventional plasmonic species (Au and Ag). We demonstrated that the an ordered array of Cu nanostructures can produce a significant extinction peak due to the excitation of surface plasmon resonance (SPR) by changing the wavelength at which it is generated to longer wavelengths away from the interband transition region. Also, we have shown that the local electric fields due to the SPR generation drastically enhanced the fluorescence signals from a porphyrin derivative and indocyanine green within visible and near infrared region above the internal transition. From these results, we confirmed that the cheaper plasmonic nanostructures have high optical antenna effects.

  • Research Products

    (7 results)

All 2014 2013 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results) Remarks (2 results)

  • [Journal Article] Metal-Enhanced Fluorescence Platforms Based on Plasmonic Ordered Copper Arrays : Wavelength Dependence of Quenching and Enhancement Effects2013

    • Author(s)
      Kosuke Sugawa, Takahiro Tamura, Hironobu Tahara, Daisuke Yamaguchi, Tsuyoshi Akiyama, Joe Otsuki, Yasuyuki Kusaka, Nobuko Fukuda, Hirobumi Ushijima
    • Journal Title

      ACS Nano 2013

      Volume: 7(11) Pages: 9997-10010

    • DOI

      10.1021/nn403925d

    • Peer Reviewed
  • [Presentation] 酸化表面を有さない銅ナノ構造体のプラズモン特性制御と光電場特性の検証2014

    • Author(s)
      須川晃資, 田村高大, 田原弘宣, 秋山毅, 大月穣
    • Organizer
      日本化学会第94回春季年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-03-29
  • [Presentation] 銅ナノ構造体を利用した可視〜近赤外領域の蛍光増強2014

    • Author(s)
      須川晃資, 田村高大, 田原弘宣, 大月穣, 秋山毅
    • Organizer
      第11回プラズモニクスシンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2014-01-24
  • [Presentation] 表面プラズモン共鳴特性が精密制御された銅ナノ構造の構築と光機能性分子の複合化と蛍光特性解析2013

    • Author(s)
      須川晃資, 田村高大, 田原弘宣, 秋山毅, 大月穣, 日下靖之, 福田伸子, 牛島洋史
    • Organizer
      第32回固体・表面光化学討論会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2013-12-11
  • [Presentation] 規則性銅ナノ構造体の表面プラズモン共鳴励起に伴うポルフィリン分子の蛍光増強2013

    • Author(s)
      須川晃資, 田村高大, 田原弘宣, 秋山毅
    • Organizer
      2013年光化学討論会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2013-09-11
  • [Remarks] 日本大学理工学部物質応用化学科超分子化学研究室 須川G学会発表

    • URL

      http://www.chem.cst.nihon-u.ac.jp/~sugawa/prespresenta.html

  • [Remarks] 日本大学理工学部物質応用化学科 超分子化学研究室 須川G学術論文・総説

    • URL

      http://www.chem.cst.nihon-u.ac.jp/~sugawa/paper.html

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Published: 2015-06-25  

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