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2013 Fiscal Year Final Research Report

A study of optimization of sensor electrodes for inproving NOx response properties

Research Project

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Project/Area Number 24750153
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental chemistry
Research InstitutionNagasaki University (2013)
Japan Fine Ceramics Center (2012)

Principal Investigator

UEDA Taro  長崎大学, 工学(系)研究科(研究院), 助教 (10524928)

Project Period (FY) 2012-04-01 – 2014-03-31
KeywordsNOxセンサ / ペロブスカイト / ジルコニア / ゾルゲル / スピンコーティング
Research Abstract

Improvements of sensing electrode of an amperometric-type zirconia-based NOx sensor were examined. As a result of investigation for making a thin-dense sensing electrode in order to enhance the NOx response, dense and thin electrodes of La0.8Sr0.2MnO3 on zirconia substrate were obtained by spin coating technique using 2-methoxyethanol solution containing La(NO3)3, Sr(OC3H7)2, Mn(CH3COO)2.4H2O mixed with ethanolamine and acetoine. It was also found that substitution of Mn with Al in La0.8Sr0.2MnO3 improves the stability in high-temperature reduction atmosphere, and the sensor shows high stability and response by optimization of composition and preparation method of the sensor electrode.

  • Research Products

    (6 results)

All 2013 2012

All Journal Article (3 results) (of which Peer Reviewed: 1 results) Presentation (3 results)

  • [Journal Article] ペロブスカイト型酸化物を用いた車載用排ガスNOxセンサの開発2013

    • Author(s)
      上田太郎, 高橋誠治
    • Journal Title

      金属

      Volume: Vol.83, No. 5 Pages: 397-401

    • URL

      http://www.agne.co.jp/kinzoku/kin1083.htm

  • [Journal Article] La系ペロブスカイト電極を用いたジルコニアNOxセンサ2013

    • Author(s)
      上田太郎, 高橋誠治
    • Journal Title

      Chemical Sensors

      Volume: Vol. 29, No. 1 Pages: 2-8

    • URL

      http://chemsens.electrochem.jp/journal/eng/eng_j.htm

  • [Journal Article] A stable sensing-electrode material in reducing atmosphere at high temperature for zirconia-based amperometric NOx sensor2013

    • Author(s)
      T. Ueda, H. Okawa, S. Takahashi
    • Journal Title

      Electrochemistry

      Volume: Vol. 81, No. 2 Pages: 74-76

    • DOI

      10.5796/electrochemistry.81.74.

    • Peer Reviewed
  • [Presentation] ジルコニアセンサ検知極の高温還元雰囲気耐久性とNOx応答特性2013

    • Author(s)
      上田太郎, 大川元, 高橋誠治
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      長野
    • Year and Date
      2013-09-14
  • [Presentation] 噴霧熱分解法によるLa_0.8Sr_0.2MnO_3多孔質球状粒子の合成とその粉末特性2013

    • Author(s)
      高橋誠治, 上田太郎, 大川元
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      長野
    • Year and Date
      2013-09-13
  • [Presentation] La系ペロブスカイト検知極を用いたジルコニアNOxセンサの応答特性2012

    • Author(s)
      上田太郎、梅田充紀、大川元、高橋誠治
    • Organizer
      日本セラミックス協会東海支部第44回東海若手セラミスト懇話会2012年夏期セミナー
    • Place of Presentation
      浜松
    • Year and Date
      2012-06-28

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Published: 2015-06-25  

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