2013 Fiscal Year Final Research Report

Fine control of specific molecular adsorptivity on a porous coordination polymer by surface modification

Research Project

Project/Area Number	24750200
Research Category	Grant-in-Aid for Young Scientists (B)
Allocation Type	Multi-year Fund
Research Field	Inorganic industrial materials
Research Institution	Tokyo University of Agriculture and Technology
Principal Investigator	KONDO Atsushi 東京農工大学, 工学(系)研究科(研究院), 助教 (60533619)
Project Period (FY)	2012-04-01 – 2014-03-31
Keywords	多孔体 / 吸着 / 配位高分子
Research Abstract	Focused on the unique function of a crystalline porous coordination polymer, which is selective CO2 adsorption accompanied with structural change, modification of the material by secondary organic ligands was performed for fine control of the adsorptivity. Based on the several analytical experiments, the modified materials contain quite small amount of the secondary organic ligands, and however they surprisingly adsorb a hydrocarbon at near room temperature that the pristine material cannot adsorb at the same condition. Evaluation of the modified materials with gas molecules clearly indicated structural change of the materials through the adsorption, indicating a success to give a new function on the materials.

(3 results)