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2013 Fiscal Year Final Research Report

Novel synthesis of sol-gel derived mesostructures for controlling their electro chemical behaviors

Research Project

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Project/Area Number 24750206
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionOsaka Prefecture University

Principal Investigator

TOKUDOME Yasuaki  大阪府立大学, 工学(系)研究科(研究院), 助教 (50613296)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywordsゾル-ゲル / 薄膜 / カーボン
Research Abstract

Mesoporous carbon films were prepared via a process that allows coating on various substrates, including metals. The mesomorphology can be controlled by changing starting composition in an appropriately-designed reaction system. Systematic characterizations have revealed that the obtained carbons exhibit structure-induced hydrophilization depending on the mesomorphology. Chemically-modified hydrophilic carbons are well known to facilitate an electrode reaction in a polar system. The materials obtained here potentially provide the similar effect.

  • Research Products

    (22 results)

All 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (13 results) Book (2 results)

  • [Journal Article] Switchable and reversible water adhesion on superhydrophobic titanate nanostructures fabricated on soft substrates : photopatternable wettability and thermomodulatable adhesivity2014

    • Author(s)
      Y. Tokudome, K. Okada, A. Nakahira, M. Takahashi
    • Journal Title

      J. Mater. Chem.

      Volume: A, 2 Pages: 58-61

    • DOI

      10.1039/c3ta13536e

    • Peer Reviewed
  • [Journal Article] Layered double hydroxide composite monoliths with three-dimensional hierarchical channels : structural control and adsorption behavior2014

    • Author(s)
      N. Tarutani, Y. Tokudome, K. Nakanishi, M. Takahashi
    • Journal Title

      RSC Advances

      Volume: 4 Pages: 16075-16080

    • DOI

      10.1039/C4RA00873A

    • Peer Reviewed
  • [Journal Article] Controlled site modification of inorganic networks in hybrid photocurable resins for high thermal crack resistance2013

    • Author(s)
      Y. Tokudome, T. Sato, M. Hidaka, M. Takahashi
    • Journal Title

      J. Sol-Gel Sci. Technol.

      Volume: 65 Pages: 318-323

    • DOI

      10.1007/s10971-012-2938-9

    • Peer Reviewed
  • [Journal Article] Layered double hydroxide (LDH)-based monolith with interconnected hierarchical channels : enhanced sorption affinity for anionic species2013

    • Author(s)
      Y. Tokudome, N. Tarutani, K. Nakanishi, M. Takahashi
    • Journal Title

      J. Mater. Chem.

      Volume: A, 1 Pages: 7702-7708

    • DOI

      10.1039/C3TA11110E

    • Peer Reviewed
  • [Journal Article] Hierarchical Nested Wrinkles on Silica-Polymer Hybrid Films : Stimuli-Responsive Micro Periodic Surface Architectures2012

    • Author(s)
      Y. Tokudome, K. Suzuki, T. Kitanaga, M. Takahashi
    • Journal Title

      Sci. Rep.

      Volume: 2:683 Pages: 1-6

    • DOI

      10.1038/srep00683

    • Peer Reviewed
  • [Journal Article] Responsive microstructures on organic/inorganic hybrid materials

    • Author(s)
      M. Takahashi, K, Suzuki, Y. Tokudome, L. Malfatti, P. Innocenzi
    • Journal Title

      J. Sol-Gel Sci. Technol.

      Volume: (in press)

    • DOI

      10.1007/s10971-014-3301-0

    • Peer Reviewed
  • [Journal Article] Micropattern Formation by Molecular Migration via UV-induced Dehydration of Block Copolymers

    • Author(s)
      K. Okada, Y. Tokudome, R. Makiura, K. Konstas, L. Malfatti, P. Innocenzi, H. Ogawa, T. Kanaya, P. Falcaro, M. Takahashi
    • Journal Title

      Adv. Funct. Mater.

      Volume: (in press)

    • DOI

      10.1002/adfm.201302812

    • Peer Reviewed
  • [Presentation] Layered Double Hydroxide (LDH)-based Monolith with Interconnected Hierarchical Channels : Enhanced Sorption Affinity for Anionic Species2014

    • Author(s)
      Y. Tokudome, N. Tarutani, K. Nakanishi, M. Takahashi
    • Organizer
      The 14th International Symposium on Biomimetic Materials Processing (BMMP-14)
    • Place of Presentation
      Gifu, Japan
    • Year and Date
      2014-01-09
  • [Presentation] Hierarchical nested wrinkle structures with stimuli-response on silica-polymer hybrid films2013

    • Author(s)
      K. Suzuki, Y. Tokudome, and M. Takahashi
    • Organizer
      The 17th International Sol-Gel Conference
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2013-08-13
  • [Presentation] Spontaneous formation of crystalline hydroxide monolith with interconnected hierarchical channels : enhanced adsorption capability for anionic species2013

    • Author(s)
      Y. Tokudome, N. Tarutani, K. Nakanishi, and M. Takahashi
    • Organizer
      The 17th International Sol-Gel Conference
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2013-08-13
  • [Presentation] Synthesis and characterization of layered double hydroxide-based monolithic material with controlled hierarchical channels2013

    • Author(s)
      N. Tarutani, Y. Tokudome, K. Nakanishi, and M. Takahashi
    • Organizer
      The 17th International Sol-Gel Conference
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2013-08-13
  • [Presentation] ブロックコポリマーのミクロ相分離構造をテンプレートにした導電性基板上へのメソポーラスカーボン薄膜の作製と構造制御2013

    • Author(s)
      中根浩平,徳留靖明,高橋雅英
    • Organizer
      日本ゾル-ゲル学会第11回討論会
    • Place of Presentation
      広島
    • Year and Date
      2013-08-02
  • [Presentation] ソフトテンプレート法を用いた導電性基板上へのメソポーラスカーボン薄膜の作製と構造制御2013

    • Author(s)
      中根浩平,徳留靖明,高橋雅英
    • Organizer
      第8回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      大津
    • Year and Date
      2013-07-26
  • [Presentation] Synthesis of Layered Double Hydroxide (LDH)-based Monolithic Composite with Hierarchical Macro/Meso Channels for Improved Ion-exchange Characteristics2013

    • Author(s)
      Y. Tokudome, N. Tarutani, K. Nakanishi, and M. Takahashi
    • Organizer
      2013 MRS spring meeting & exhibit
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-04-04
  • [Presentation] ナノ粒子二次元配列マスクを用いた表面微細構造の形成2012

    • Author(s)
      矢木信介,徳留靖明,高橋雅英,西井準治
    • Organizer
      第53回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      北海道
    • Year and Date
      2012-10-25
  • [Presentation] ブロックコポリマーの光誘起相転移を利用した階層的高次構造酸化物薄膜の形成2012

    • Author(s)
      岡田健司,徳留靖明,高橋雅英, P. Falcaro
    • Organizer
      第53回ガラスおよびフォトニクス材料討論会
    • Place of Presentation
      北海道
    • Year and Date
      2012-10-25
  • [Presentation] 組成傾斜メソポーラスシリカ膜における階層的高次構造の形成2012

    • Author(s)
      徳留靖明,朝倉元樹,鈴木一正,高橋雅英
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-20
  • [Presentation] Spontaneous Formation of Macroporous Inorganic Materials : Synthesis Strategy for Mixed Metal Oxides and Phosphates with a Monolithic Form2012

    • Author(s)
      Y. Tokudome, N. Tarutani, K. Nakanishi, and M. Takahashi
    • Organizer
      2012 OPU-KIST-ECUST Joint Symposium on Advanced Materials and Applications
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2012-09-10
  • [Presentation] Blue-shifted Luminescence from Alq_3 Isolated in Silica Matrix : Analysis by Solid-State NMR2012

    • Author(s)
      Y. Tokudome, M. Fukuchi, F. Suzuki, M. Takahashi, and H. Kaji
    • Organizer
      9th International Conference on Electroluminescence & Organic Optoelectronics
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2012-09-04
  • [Presentation] Monolithic Columns with Extended Materials Compositions2012

    • Author(s)
      K. Nakanishi, K. Kanamori, K. Morisato, G. Hasegawa, Y. Tokudome
    • Organizer
      38th International Symposium on High Performance Liquid Phase Separations and Related Techniques
    • Place of Presentation
      Anaheim, CA USA
    • Year and Date
      2012-06-20
  • [Book] 月刊「化学」68[10]2014

    • Author(s)
      徳留靖明、高橋雅英
    • Total Pages
      72-73
    • Publisher
      化学同人
  • [Book] ゾル-ゲル法の最新応用と展望(第1章7項)2014

    • Author(s)
      高橋雅英、徳留靖明
    • Total Pages
      70-78
    • Publisher
      シーエムシー出版

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Published: 2015-06-25  

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