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2013 Fiscal Year Final Research Report

Development of a method to control biomass pyrolysis using ionic liquid

Research Project

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Project/Area Number 24760631
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionKyushu University

Principal Investigator

KUDO Shinji  九州大学, 先導物質化学研究所, 助教 (70588889)

Project Period (FY) 2012-04-01 – 2014-03-31
Keywordsバイオマス / セルロース / 熱分解 / イオン液体
Research Abstract

Sulfonate ionic liquids promoted dehydration of cellulose when their mixture was heated under inert gas stream, which resulted in a selective production of levoglucosenone that is a high-value added chemical. Similar results were obtained even when glucose and its oligomer and polymer were used as the source of levoglucosenone, although cellulose was the most promising starting material. On the basis of knowledge obtained in the experiment, a new and more efficient method for levoglucosenone production was proposed for the study in future.

  • Research Products

    (5 results)

All 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (3 results)

  • [Journal Article] Sulfonate Ionic Liquid as a Stable and Active Catalyst for Levoglucosenone Production from Saccharides via Catalytic Pyrolysis2013

    • Author(s)
      S. Kudo, Z. Zhou, K. Yamasaki, K. Norinaga, J.-i. Hayashi
    • Journal Title

      Catalysts

      Volume: 3 Pages: 757-773

    • DOI

      10.3390/catal3040757

    • Peer Reviewed
  • [Journal Article] Applications of Catalysis in the Selective Conversion of Lignocellulosic Biomass by Pyrolysis2012

    • Author(s)
      S. Kudo, K. Norinaga, J.-i. Hayashi
    • Journal Title

      Journal of Novel Carbon Resource Sciences

      Volume: 6 Pages: 1-8

    • URL

      http://ncrs.cm.kyushu-u.ac.jp/assets/files/JNCRS/JNCRS_Vol6_01-08.pdf

    • Peer Reviewed
  • [Presentation] Catalysis of ionic liquid for selective formation of levoglucosenone from pyrolysis of cellulose2013

    • Author(s)
      S. Kudo, K. Yamasaki, Z. Zhou, K. Norinaga, J.-i. Hayashi
    • Organizer
      2nd International Symposium on Green Chemistry
    • Place of Presentation
      La Rochelle, France
    • Year and Date
      20130521-24
  • [Presentation] Intra-monomer- unit dehydration of cellulose under catalysis of ionic liquid toward selective production of levoglucosenone2012

    • Author(s)
      K. Yamasaki, Z. Zhou, S. Kudo, K. Norinaga, J.-i. Hayashi
    • Organizer
      The 25th International Symposium on Chemical Engineering
    • Place of Presentation
      Okiwana, Japan
    • Year and Date
      20121214-15
  • [Presentation] セルロース熱分解に対するイオン液体の触媒作用2012

    • Author(s)
      周振巍,工藤真二,則永行庸,林潤一郎
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      仙台
    • Year and Date
      20120919-21

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Published: 2015-06-25  

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