2013 Fiscal Year Final Research Report
Development and Application of Organocatalyst for Activation of Gas Molecule
| Project/Area Number |
24790023
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kitasato University |
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Principal Investigator |
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | 有機分子触媒 / 有機ホウ素化合物 / 気体分子 / 水素化反応 |
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| Research Abstract |
Even though the use of homogeneous transition metal catalytic hydrogenation is one of the key technologies, transition metal complexes are expensive, and the removal of metal impurities from the reaction product is generally required. Recently, metal-free hydrogenation has been accomplished using tris(perfluorophenyl)borane. In order to develop the reaction system, we synthesized new class of triaryl boranes. As the result, it has been found that triaryl boranes are stabilized by neighboring group participation.
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