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2014 Fiscal Year Final Research Report

Development of novel cascade reactions of alkyne derivatives for the efficient synthetic procedures of heterocycles

Research Project

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Project/Area Number 24790024
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Chemical pharmacy
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

SAITO AKIO  東京農工大学, 工学(系)研究科(研究院), 准教授 (10339103)

Project Period (FY) 2012-04-01 – 2015-03-31
Keywordsアルキン / 複素環 / 金触媒 / ヨウ素試薬
Outline of Final Research Achievements

We have developed the efficient synthetic methods of heterocyclic compounds by means of cascade reactions and multi-component reactions based on each of the following reactions: 1) syntheses of polycyclic isochromane and benzofuran via Au-catalyzed carboalkoxylation reactions, 2) syntheses of oxazoles and imidazoles by metal-free [2+2+1]annulation reactions, and 3) syntheses of fluorinated oxazoles through hypervalent iodine-mediated cycloisomerization-fluorination reaction.

Free Research Field

有機合成化学

URL: 

Published: 2016-06-03  

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