2016 Fiscal Year Final Research Report
Development of new synthesis methods of propene without using naphtha
Project/Area Number |
25249114
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Catalyst/Resource chemical process
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Research Institution | Chuo University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
田中 大士 中央大学, 公私立大学の部局等, 助教 (00528002)
本田 正義 国立研究開発法人理化学研究所, その他部局等, 研究員 (70734078)
|
Project Period (FY) |
2013-04-01 – 2017-03-31
|
Keywords | プロピレン / バイオエタノール / シェールガス / 過酸化水素 / アンモニア / プラズマ |
Outline of Final Research Achievements |
In order to convert current petrochemical processes to low carbon consumption type, three catalytic reaction systems were developed for (1) synthesizing propylene from bioethanol, (2) converting shale gas-derived ethane to ethene, then to butenes, and finally to propene via metathesis, and (3) changing energy-intensive reactions such as hydrogen peroxide and ammonia formations into energy saving types. In the first item, we developed Sc/In2O3 and clarified that the reaction proceeds through acetaldehyde and acetone. In the second item, we found a high catalytic activity of Ni/SiO2 and revealed that the reaction proceeds with the estimated mechanism. Pt-supported Pd catalysts were developed for H2O2 production and plasma electrode catalyst method for effective NH3 production.
|
Free Research Field |
固体触媒化学
|