Preparation of Organic-Inorganic Hybrid Monoliths and Their Functions

2016 Fiscal Year Final Research Report

• Project/Area Number: 25288090
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Organic and hybrid materials
• Research Institution: Osaka University
• Principal Investigator: Uyama Hiroshi 大阪大学, 工学(系)研究科(研究院), 教授 (70203594)
• Project Period (FY): 2013-04-01 – 2017-03-31
• Keywords: モノリス / 有機無機ハイブリッド / 相分離 / 多孔質体 / アフィニティークロマトグラフィー / 鈴木-宮浦カップリング / 固定化触媒

Outline of Final Research Achievements

Monolith, a three-dimensional porous material having a continuous interconnected nanoscale pore structure in a single piece, has received much attention as functional materials. This study deals with development of functional organic-inorganic monoliths based on thermally induced phase separation technique for fabrication of polymer monoliths. For application of immobilized catalysts, Pd was loaded on monoliths of acrylic resin or poly(ethylene-co-vinyl alcohol), and the obtained organic-inorganic monolith was used as catalyst for Suzuki-Miyaura coupling. The metal-immobilized monolith was applied for matrix of affinity chromatography.

Free Research Field

有機無機ハイブリッド