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2015 Fiscal Year Annual Research Report

新規面方位制御技術を用いた非極性窒化ガリウムおよび窒化物半導体結晶の創製

Research Project

Project/Area Number 25390064
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

村上 尚  東京農工大学, 工学(系)研究科(研究院), 准教授 (90401455)

Project Period (FY) 2013-04-01 – 2016-03-31
Keywords窒化物半導体 / 選択成長 / 半極性 / 基板加工 / 異方性エッチング / 砒化ガリウム
Outline of Annual Research Achievements

白色LEDをはじめとする照明用途光デバイスの高効率化、電力変換を担うパワーデバイスの高耐圧化、低損失化のために高品質のIII族窒化物半導体結晶の創製が求められている。本研究では新規の面方位制御技術を提案し、非極性面III族窒化物半導体の成長方法、結晶内貫通転位低減方法の確立のためのGaAs基板加工およびそれに続く結晶成長の検討を行った。
平成25年度において、GaAs基板のリン酸および過酸化水素による加工条件の確立およびInN選択成長の基本条件の検討、平成26年度はInN成長の面方位選択性向上のための成長条件の確立、GaAs(111)Aファセット面を選択的に形成するエッチング条
件の確立およびその上のInN選択成長、長時間成長による半極性InN膜の形成技術を確立した。また、H25年度において、GaN成長を行う際成長温度の高温化に伴ってGaAs基板劣化が生じること、また、H26年度にGaAs基板加工において(111)A面ファセットは平坦な表面が得づらいのに対し、(111)B面ファセットは比較的良好な表面が形成できることが明らかになったことから、H27年度は積極的に(111)B面上のGaN成長を検討した。GaAs(111)B面上へのGaN成長は原子配列の関係からN極性GaN成長となることから、従来の成長方法ではその制御が難しく、N極性GaN成長が支配的となるトリハライド気相成長(THVPE)法を導入することとした。現有のMOVPE成長装置に三塩化ガリウム固体原料供給系を付加し、NH3と反応させることでN極性GaNを成長できるようにした。初期検討として、サファイアおよびN極性GaN自立基板を種基板としてTHVPE法によりGaNの成長を行い、高温成長により劇的に結晶品質(転位密度、不純物濃度低減)の向上が可能であることを見出した。

  • Research Products

    (14 results)

All 2016 2015

All Journal Article (2 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 2 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 5 results)

  • [Journal Article] Investigation of NH3 input partial pressure for N-polarity InGaN growth on GaN substrates by tri-halide vapor phase epitaxy2016

    • Author(s)
      Takahide Hirasaki, Tomoyasu Hasegawa, Misaki Meguro, Quang Tu Thieu, Hisashi Murakami*, Yoshinao Kumagai, Bo Monemar, Akinori Koukitu
    • Journal Title

      Journal of Applied Physics

      Volume: 55 Pages: 05FA01-1-4

    • DOI

      10.7567/JJAP.55.05FA01

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High rate InN growth by two-step precursor generation hydride vapor phase epitaxy2015

    • Author(s)
      Rie Togashi, Quang Tu Thieu, Hisashi Murakami, Yoshihiro Ishitani, Yoshinao Kumagai, Bo Monemar, Akinori Koukitu
    • Journal Title

      Journal of Crystal Growth

      Volume: 422 Pages: 15-19

    • DOI

      10.1016/j.jcrysgro.2015.04.019

    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Growth of Thick InGaN and GaN by Tri-Halide Vapor Phase Epitaxy with high rate2015

    • Author(s)
      Hisashi Murakami, Takahide Hirasaki, Quang Tu Thieu, Rie Togashi, Yoshinao Kumagai, Akinori Koukitu
    • Organizer
      Collaborative Conference on Crystal Growth (3CG)
    • Place of Presentation
      Eaton Hotel, Hong Kong
    • Year and Date
      2015-12-15 – 2015-12-15
    • Int'l Joint Research / Invited
  • [Presentation] HVPE growth of the group III nitrides2015

    • Author(s)
      A. Koukitu, Y. Kumagai, H. Murakami
    • Organizer
      14th Akasaki Research Center Symposium
    • Place of Presentation
      Nagoya University, Aichi, Japan
    • Year and Date
      2015-11-20 – 2015-11-20
    • Int'l Joint Research / Invited
  • [Presentation] Influence of NH3 input partial pressure on N-polarity InGaN growth by tri-halide vapor phase epitaxy2015

    • Author(s)
      Takahide Hirasaki, Tomoyasu Hasegawa, Misaki Meguro, Quang Tu Thieu, Hisashi Murakami, Yoshinao Kumagai, Bo Monemar, Akinori Koukitu
    • Organizer
      6th International Symposium on Growth of III-Nitrides (ISGN-6)
    • Place of Presentation
      Act City Hamamatsu, Shizuoka, Japan
    • Year and Date
      2015-11-10 – 2015-11-10
    • Int'l Joint Research
  • [Presentation] Tri-Halide Vapor Phase Epitaxy of Thick GaN and InGaN Layers2015

    • Author(s)
      Hisashi Murakami, Takahide Hirasaki, Quang Tu Thieu, Rie Togashi, Yoshinao Kumagai, Kou Matsumoto, Akinori Koukitu
    • Organizer
      9th International Workshop on Bulk Nitride Semiconductors (IWBNS-IX)
    • Place of Presentation
      Hansol Oak Valley, Wonju, Korea
    • Year and Date
      2015-11-04 – 2015-11-04
    • Int'l Joint Research / Invited
  • [Presentation] Thick (>10 μm) and High Crystalline Quality InGaN Growth on GaN(000-1) Substrate by Tri-Halide Vapor Phase Epitaxy2015

    • Author(s)
      Takahide Hirasaki, Tomoyasu Hasegawa, Misaki Meguro, Quang Tu Thieu, Hisashi Murakami, Yoshinao Kumagai, Bo Monemar, Akinori Koukitu
    • Organizer
      9th International Workshop on Bulk Nitride Semiconductors (IWBNS-IX)
    • Place of Presentation
      Hansol Oak Valley, Wonju, Korea
    • Year and Date
      2015-11-04 – 2015-11-04
    • Int'l Joint Research / Invited
  • [Presentation] トリハライド気相成長法によるIn組成5%のInGaN厚膜(>10μm)成長2015

    • Author(s)
      目黒 美佐稀、平﨑 貴英、長谷川 智康、ティユ クァン トゥ、村上 尚、熊谷 義直、Bo Monemar、纐纈 明伯
    • Organizer
      第4回結晶工学未来塾
    • Place of Presentation
      東京農工大学(東京都小金井市)
    • Year and Date
      2015-10-29 – 2015-10-29
  • [Presentation] Effect of NH3 Input Partial Pressure on InGaN Growth by Tri-Halide Vapor Phase Epitaxy2015

    • Author(s)
      Takahide Hirasaki, Tomoyasu Hasegawa, Misaki Meguro, Hisashi Murakami, Yoshinao Kumagai, Bo Monemar and Akinori Koukitu
    • Organizer
      34th Electronic Materials Symposium (EMS-34)
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2015-07-16 – 2015-07-16
  • [Presentation] Dependences of input InCl3 ratio and growth temperature in InGaN growth by Tri-Halide Vapor Phase Epitaxy2015

    • Author(s)
      Misaki Meguro, Takahide Hirasaki, Tomoyasu Hasegawa, Hisashi Murakami, Yoshinao Kumagai, Bo Monemar and Akinori Koukitu
    • Organizer
      34th Electronic Materials Symposium (EMS-34)
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2015-07-15 – 2015-07-15
  • [Presentation] Growth of GaN and InGaN thick epitaxial layers by tri-halide vapor phase epitaxy2015

    • Author(s)
      Hisashi Murakami, Takahide Hirasaki, Quang Tu Thieu, Rie Togashi, Yoshinao Kumagai, Kou Matsumoto, Akinori Koukitu
    • Organizer
      Workshop on Frontier Photonic and Electronic Materials and Devices
    • Place of Presentation
      Kyoto University, Kyoto, Japan
    • Year and Date
      2015-07-13 – 2015-07-13
    • Int'l Joint Research / Invited
  • [Presentation] トリハライド気相成長法を用いたInGaN成長におけるNH3供給分圧の影響2015

    • Author(s)
      平崎貴英,長谷川智康,目黒美佐稀,村上尚,熊谷義直,Bo Monemar,纐纈明伯
    • Organizer
      日本結晶成長学会ナノ構造・エピタキシャル成長分科会第7回窒化物半導体結晶成長講演会
    • Place of Presentation
      東北大学片平キャンパス(宮城県仙台市)
    • Year and Date
      2015-05-08 – 2015-05-08
  • [Presentation] Growth of GaN on r-plane sapphire substrate by tri-halide vapor phase epitaxy2015

    • Author(s)
      A. Shiono, N. Takekawa, H. Murakami, Y. Kumagai and A. Koukitu
    • Organizer
      Conference on LED and Its Industrial Application '15 (LEDIA '15)
    • Place of Presentation
      Pacifico Yokohama, Kanagawa, Japan
    • Year and Date
      2015-04-23 – 2015-04-23
    • Int'l Joint Research
  • [Presentation] Calculation of thermochemical data for the growth of III-nitrides by vapor phase epitaxy2015

    • Author(s)
      N. Takekawa, H. Murakami, Y. Kumagai and A. Koukitu
    • Organizer
      Conference on LED and Its Industrial Application '15 (LEDIA '15)
    • Place of Presentation
      Pacifico Yokohama, Kanagawa, Japan
    • Year and Date
      2015-04-23 – 2015-04-23
    • Int'l Joint Research

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Published: 2017-01-06  

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