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2015 Fiscal Year Annual Research Report

450 mm直径Si単結晶育成における点欠陥の精密制御に関する基礎研究

Research Project

Project/Area Number 25390069
Research InstitutionOkayama Prefectural University

Principal Investigator

末岡 浩治  岡山県立大学, 情報工学部, 教授 (30364095)

Project Period (FY) 2013-04-01 – 2016-03-31
Keywords半導体 / シリコン単結晶 / 点欠陥 / 熱応力 / 大口径化
Outline of Annual Research Achievements

本研究の全体的な構想は,半導体Si単結晶育成において,熱応力の影響を考慮した点欠陥挙動シミュレータを開発し,産業界における450mm直径の無欠陥Si単結晶の実現に貢献することである.第一原理計算法を用いて熱応力が点欠陥の形成エンタルピーに与える影響を定量的に求め,その結果をVoronkov理論に適用する手法に特徴がある.
平成25年度には等方性応力の効果について,さらに平成26年度には平面応力の効果について研究した結果,現実の固液界面近傍の熱応力成分である平面応力を仮定した場合,Voronkovの臨界v/G値の変動を精度よく再現できることを示した.また,無欠陥Si結晶を製造可能な育成条件を明示する成果を得た.さらに,ドーパントが点欠陥濃度に与える影響についても,そのモデル化に成功した.
最終年度である平成27年度は,この応力効果を組み込んだ結晶成長の数値シミュレータ開発に取り組んだ.平面応力が点欠陥のパラメータに与える影響を考慮してgrown-in欠陥分布をシミュレートした結果,OSFリング位置などの再現に成功した.この成果について,現在,学術論文を作成中である.さらに,CZ-Si結晶中に取り込まれる格子間酸素が点欠陥に与える効果についても計算し,点欠陥の形成エントロピーも考慮することで,原子空孔濃度の酸素濃度依存性を説明することにも成功した.Si結晶中の点欠陥挙動に関する理論計算について,米国電気化学会からReview論文を依頼され,3月に出版した.

Remarks

研究成果を掲載しています.

  • Research Products

    (14 results)

All 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (5 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results) Presentation (5 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results) Book (1 results) Remarks (1 results)

  • [Int'l Joint Research] ゲント大学(ベルギー)

    • Country Name
      BELGIUM
    • Counterpart Institution
      ゲント大学
  • [Int'l Joint Research] ワルシャワ工科大学(ポーランド)

    • Country Name
      POLAND
    • Counterpart Institution
      ワルシャワ工科大学
  • [Journal Article] Review: Properties of Intrinsic Point Defects in Si and Ge Assessed by Density Functional Theory2016

    • Author(s)
      Koji Sueoka, Eiji Kamiyama, Piotr Spiewak, and Jan Vanhellemont
    • Journal Title

      ECS Journal of Solid State Science and Technology

      Volume: 5 Pages: P3176-P3195

    • DOI

      10.1149/2.0251604jss

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] シリコン単結晶育成中の点欠陥挙動に与える置換型ドーパントと熱応力の効果2016

    • Author(s)
      末岡 浩治
    • Journal Title

      表面科学

      Volume: 37 Pages: 116-121

    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Comment on “Investigations of interstitial generations near growth interface depending on crystal pulling rates during CZ silicon growth by detaching from the melt” by T. Abe et al. [J. CrystGrowth 434 (2016) 128-137]2016

    • Author(s)
      Jan Vanhellemont, Eiji Kamiyama, Kozo Nakamura, and Koji Sueoka
    • Journal Title

      J. Crystal Growth

      Volume: 印刷中 Pages: 印刷中

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The Hakoniwa method, an approach to predict material properties based on statistical thermodynamics and ab initio calculations2016

    • Author(s)
      Eiji Kamiyama, Ryo Matsutani, Ryo Suwa, Jan Vanhellemont, and Koji Sueoka
    • Journal Title

      Materials Science in Semiconductor Processing

      Volume: 43 Pages: 209-213

    • DOI

      org/10.1016/j.mssp.2015.12.023

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Density functional theory calculations for estimation of gettering sites of C, H, intrinsic point defects and related complexes in Si wafers2016

    • Author(s)
      Sho Shirasawa, Koji Sueoka, Tadashi Yamaguchi, and Kazuyoshi Maekawa
    • Journal Title

      Materials Science in Semiconductor Processing

      Volume: 44 Pages: 13-17

    • DOI

      org/10.1016/j.mssp.2016.01.001

    • Peer Reviewed
  • [Presentation] Modeling of intrinsic point defect properties and clustering during single crystal silicon and germanium growth from a melt2015

    • Author(s)
      Jan Vanhellemont, Eiji Kamiyama, Kozo Nakamura, Piotr Spiewak, and Koji Sueoka
    • Organizer
      The 8th International Workshop on Modeling in Crystal Growth (IWMCG-8)
    • Place of Presentation
      Spa, Belgium
    • Year and Date
      2015-11-15 – 2015-11-18
    • Int'l Joint Research / Invited
  • [Presentation] Theoretical study of the impact of stress and interstitial oxygen on the behavior of intrinsic point defects in growing Czochralski Si crystals2015

    • Author(s)
      Koji Sueoka, Kozo Nakamura, and Jan Vanhellemont
    • Organizer
      The 8th International Workshop on Modeling in Crystal Growth (IWMCG-8)
    • Place of Presentation
      Spa, Belgium
    • Year and Date
      2015-11-15 – 2015-11-18
    • Int'l Joint Research
  • [Presentation] Density functional theory study of dopant effect on formation energy of intrinsic point defects in germanium crystals2015

    • Author(s)
      Syunta Yamaoka, Koji Kobayashi, Koji Sueoka, and Jan Vanhellemont
    • Organizer
      The 8th International Workshop on Modeling in Crystal Growth (IWMCG-8)
    • Place of Presentation
      Spa, Belgium
    • Year and Date
      2015-11-15 – 2015-11-18
    • Int'l Joint Research
  • [Presentation] First principles calculation of dopant impact on formation energy of intrinsic point defects in single crystal silicon2015

    • Author(s)
      Koji Kobayashi, Syunta Yamaoka, Koji Sueoka, and Jan Vanhellemont
    • Organizer
      The 8th International Workshop on Modeling in Crystal Growth (IWMCG-8)
    • Place of Presentation
      Spa, Belgium
    • Year and Date
      2015-11-15 – 2015-11-18
    • Int'l Joint Research
  • [Presentation] Theoretical study of the impact of stress and interstitial oxygen on the behavior of intrinsic point defects in growing CZ-Si crystals2015

    • Author(s)
      K. Sueoka, K. Nakamura, and J. Vanhellemont
    • Organizer
      GADEST 2015
    • Place of Presentation
      Bad Staffelstein, Germany
    • Year and Date
      2015-09-20 – 2015-09-25
    • Int'l Joint Research
  • [Book] Defects and Impurities in Silicon Materials2015

    • Author(s)
      Jan Vanhellemont, Kozo Nakamura, Eiji Kamiyama, and Koji Sueoka
    • Total Pages
      59
    • Publisher
      Springer
  • [Remarks] 岡山県立大学 情報工学部 情報通信工学科 応用物理学研究室

    • URL

      http://www-apl.c.oka-pu.ac.jp/

URL: 

Published: 2017-01-06  

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